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On the Tributylphosphate-Based Super-Concentrated HCl System
Alternative TitleOn the Tributylphosphate-Based Super-Concentrated HCl System
Guo Lin1; Huang Kun3; Guo Ran2; He Anqi2; Weng Shifu2; Yang Zhanlan2; Zhao Ying3; Xia Jinming4; Xu Yizhuang2; Kang Tingguo1; Wu Jinguang2
2015
Source PublicationSPECTROSCOPY AND SPECTRAL ANALYSIS
ISSN1000-0593
Volume35Issue:8Pages:2241-2245
AbstractWe reported a new super-concentrated hydrochloric acid system prepared by using tri-n-butyl phosphate (TBP)-constructed reversed micelles at ambient temperature and pressure. According to the titration result, the molar ratio of H+ to H2O (denoted as n(H)+/nH(2)O) in the super-concentrated HCl range from 0. 50 to 1. 50 which are higher than that in saturated aqueous HCl bulk solution (0. 28). Significant a moment of hydrochloric acid is confined in W/O reversed micelles. Therefore, the behavior and status of HCl are different from those of conventional bluk solution. FTIR spectroscopic results demonstrate that a significant amount of HCl remains in the molecular form rather than being ionized into H+ and Cl-. Thus, super-concentrated HCl provides an extraordinary chemical environment which may have significant influence on certain substances. We found that the color of the solution is reddish brown when copper ion is dissolved in super-concentrated HCl, while the color of the saturated HCl aqueous solution (37 Wt%) containing copper ion is green. That is to say, the copper ions exist in a special state under the unique chemical environment of super-concentrated HCl. UV-Vis-NIR spectra indicate that both d-d transition band and charge transfer transition band of copper ions in super-concentrated HCl solution underwent significant variations. In addition, copper ions also have obvious influence on the hydrogen bond network among HCl in the super-concentrated HCl solution. Remarkable variation is introduced in the H-Cl stretching band in FTIR spectra.
KeywordACID Tributyl phosphate (TBP) Super-concentrated HCl n(H)+/nH(2)O Copper ion
Indexed ByCSCD
Language英语
CSCD IDCSCD:5481746
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/147839
Collection中国科学院金属研究所
Affiliation1.辽宁大学
2.北京大学
3.中国科学院
4.中国科学院金属研究所
Recommended Citation
GB/T 7714
Guo Lin,Huang Kun,Guo Ran,et al. On the Tributylphosphate-Based Super-Concentrated HCl System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2015,35(8):2241-2245.
APA Guo Lin.,Huang Kun.,Guo Ran.,He Anqi.,Weng Shifu.,...&Wu Jinguang.(2015).On the Tributylphosphate-Based Super-Concentrated HCl System.SPECTROSCOPY AND SPECTRAL ANALYSIS,35(8),2241-2245.
MLA Guo Lin,et al."On the Tributylphosphate-Based Super-Concentrated HCl System".SPECTROSCOPY AND SPECTRAL ANALYSIS 35.8(2015):2241-2245.
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