IMR OpenIR
Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O
Alternative TitleSynthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O
SUNYaGuang; GAOEnJun; WEIDeZhou; LIUYiNan
2005
Source Publication结构化学
ISSN0254-5861
Volume24.0Issue:011Pages:1298-1301
AbstractA novel complex Cd2(phen)4(phth)2·4H2O has been synthesized by the reaction of Hzphth(phthalic acid) and phen(1,10-phenanthroline) with Cd(Ⅱ) in ethanol-water solution. X-ray crystal structure analysis shows it crystallizes in triclinic, space group PI- with a = 10.619(3), b = 12.560(4), c = 12.651(4) A, a = 98.775(5), β = 109.035(5),γ = 113-576(5)°, C32H24CdN4O6, Mr= 672.95, V = 1381.7(7)A^3, Rint = 0.0358, Z = 2, Dc= 1.618 g/cm^3,μ = 0.845 mm^-1, -6 ≤h≤13, -15 ≤k ≤13, -15 ≤l≤14, F(000) = 680, S = 1.038, R = 0.0480 and wR = 0.0849 for 3992 observed reflections (1 〉 2σ(Ⅰ)). Phth bridges Cd(Ⅱ) to form a macrocyclic compound, and a 2D supramolecular motif is formed through hydrogen bonds and π-π interaction.
Other AbstractA novel complex Cd2(phen)4(phth)2·4H2O has been synthesized by the reaction of Hzphth(phthalic acid) and phen(1,10-phenanthroline) with Cd(Ⅱ) in ethanol-water solution. X-ray crystal structure analysis shows it crystallizes in triclinic, space group PI- with a = 10.619(3), b = 12.560(4), c = 12.651(4) A, a = 98.775(5), β = 109.035(5),γ = 113-576(5)°, C32H24CdN4O6, Mr= 672.95, V = 1381.7(7)A^3, Rint = 0.0358, Z = 2, Dc= 1.618 g/cm^3,μ = 0.845 mm^-1, -6 ≤h≤13, -15 ≤k ≤13, -15 ≤l≤14, F(000) = 680, S = 1.038, R = 0.0480 and wR = 0.0849 for 3992 observed reflections (1 〉 2σ(Ⅰ)). Phth bridges Cd(Ⅱ) to form a macrocyclic compound, and a 2D supramolecular motif is formed through hydrogen bonds and π-π interaction.
Keyword 晶体结构 氢焊接法 合成方法 水成反应
Indexed ByCSCD
Language中文
CSCD IDCSCD:2164814
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/149654
Collection中国科学院金属研究所
Affiliation中国科学院金属研究所
Recommended Citation
GB/T 7714
SUNYaGuang,GAOEnJun,WEIDeZhou,等. Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O[J]. 结构化学,2005,24.0(011):1298-1301.
APA SUNYaGuang,GAOEnJun,WEIDeZhou,&LIUYiNan.(2005).Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O.结构化学,24.0(011),1298-1301.
MLA SUNYaGuang,et al."Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O".结构化学 24.0.011(2005):1298-1301.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[SUNYaGuang]'s Articles
[GAOEnJun]'s Articles
[WEIDeZhou]'s Articles
Baidu academic
Similar articles in Baidu academic
[SUNYaGuang]'s Articles
[GAOEnJun]'s Articles
[WEIDeZhou]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[SUNYaGuang]'s Articles
[GAOEnJun]'s Articles
[WEIDeZhou]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.