Synthesis and Structure of a Novel Macrocyclic Complex Cd2（phen）4（phth）2·4H2O

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	Synthesis and Structure of a Novel Macrocyclic Complex Cd2（phen）4（phth）2·4H2O
其他题名	Synthesis and Structure of a Novel Macrocyclic Complex Cd2（phen）4（phth）2·4H2O
	SUNYaGuang; GAOEnJun; WEIDeZhou; LIUYiNan
	2005
发表期刊	结构化学
ISSN	0254-5861
卷号	24.0 期号:011 页码:1298-1301
摘要	A novel complex Cd2（phen）4（phth）2·4H2O has been synthesized by the reaction of Hzphth（phthalic acid） and phen（1,10-phenanthroline） with Cd（Ⅱ） in ethanol-water solution. X-ray crystal structure analysis shows it crystallizes in triclinic, space group PI- with a = 10.619（3）, b = 12.560（4）, c = 12.651（4） A, a = 98.775（5）, β = 109.035（5）,γ = 113-576（5）°, C32H24CdN4O6, Mr= 672.95, V = 1381.7（7）A^3, Rint = 0.0358, Z = 2, Dc= 1.618 g/cm^3,μ = 0.845 mm^-1, -6 ≤h≤13, -15 ≤k ≤13, -15 ≤l≤14, F（000） = 680, S = 1.038, R = 0.0480 and wR = 0.0849 for 3992 observed reflections （1 〉 2σ（Ⅰ））. Phth bridges Cd（Ⅱ） to form a macrocyclic compound, and a 2D supramolecular motif is formed through hydrogen bonds and π-π interaction.
其他摘要	A novel complex Cd2（phen）4（phth）2·4H2O has been synthesized by the reaction of Hzphth（phthalic acid） and phen（1,10-phenanthroline） with Cd（Ⅱ） in ethanol-water solution. X-ray crystal structure analysis shows it crystallizes in triclinic, space group PI- with a = 10.619（3）, b = 12.560（4）, c = 12.651（4） A, a = 98.775（5）, β = 109.035（5）,γ = 113-576（5）°, C32H24CdN4O6, Mr= 672.95, V = 1381.7（7）A^3, Rint = 0.0358, Z = 2, Dc= 1.618 g/cm^3,μ = 0.845 mm^-1, -6 ≤h≤13, -15 ≤k ≤13, -15 ≤l≤14, F（000） = 680, S = 1.038, R = 0.0480 and wR = 0.0849 for 3992 observed reflections （1 〉 2σ（Ⅰ））. Phth bridges Cd（Ⅱ） to form a macrocyclic compound, and a 2D supramolecular motif is formed through hydrogen bonds and π-π interaction.
关键词	镉晶体结构氢焊接法合成方法水成反应
收录类别	CSCD
语种	中文
CSCD记录号	CSCD:2164814
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/149654
专题	中国科学院金属研究所
作者单位	中国科学院金属研究所
推荐引用方式 GB/T 7714	SUNYaGuang,GAOEnJun,WEIDeZhou,等. Synthesis and Structure of a Novel Macrocyclic Complex Cd2（phen）4（phth）2·4H2O[J]. 结构化学,2005,24.0(011):1298-1301.
APA	SUNYaGuang,GAOEnJun,WEIDeZhou,&LIUYiNan.(2005).Synthesis and Structure of a Novel Macrocyclic Complex Cd2（phen）4（phth）2·4H2O.结构化学,24.0(011),1298-1301.
MLA	SUNYaGuang,et al."Synthesis and Structure of a Novel Macrocyclic Complex Cd2（phen）4（phth）2·4H2O".结构化学 24.0.011(2005):1298-1301.