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Microstructure Variation of Pellets Containing Ferrous Dust during Carbonation Consolidation
Alternative TitleMicrostructure Variation of Pellets Containing Ferrous Dust during Carbonation Consolidation
Shi Yan1; Liu Shimeng2; Hu Changqing2; Zhang Yuzhu2
2015
Source PublicationJOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
ISSN1006-706X
Volume22Issue:2Pages:128-134
AbstractThe carbonation and microstructure characteristics of pellets containing ferrous dusts were investigated during carbonation consolidation at different reaction temperatures and CO2 partial pressures. The results indicated that green pellets had loose and network supporting structure with initial strength. and large cracks and pores existed in the pellets. The carbonation reaction was controlled by interfacial chemical reaction at the initial fast stage, which limited diffusion and thus caused the reaction rate to decrease. With increasing reaction temperature and CO2 partial pressure, the conversion rates of CaO and the number of microcrystalline CaCO3 particles increased, and the volume expansion of CaC2O3 led to a decrease in the open porosity. average pore size and specific surface area of the pellets. Micro-pores were occluded, and the number of smaller pores (diameter less than 50 nm) increased, thereby resulting in the more compact and uniform structure of carbonated pellets. Simultaneously, the dense structure prevented CO2 diffusion into the product layer. affecting the increase in carbonation conversion rate.
Other AbstractThe carbonation and microstructure characteristics of pellets containing ferrous dusts were investigated during carbonation consolidation at different reaction temperatures and CO_2 partial pressures. The results indicated that green pellets had loose and network supporting structure with initial strength, and large cracks and pores existed in the pellets. The carbonation reaction was controlled by interfacial chemical reaction at the initial fast stage, which limited diffusion and thus caused the reaction rate to decrease. With increasing reaction temperature and CO_2 partial pressure, the conversion rates of CaO and the number of microcrystalline CaCO_3 particles increased, and the volume expansion of CaCO_3 led to a decrease in the open porosity, average pore size and specific surface area of the pellets. Micro-pores were occluded, and the number of smaller pores (diameter less than 50 nm) increased, thereby resulting in the more compact and uniform structure of carbonated pellets. Simultaneously, the dense structure prevented CO_2 diffusion into the product layer, affecting the increase in carbonation conversion rate.
KeywordBASIC OXYGEN STEEL IRON-OXIDE PELLETS HIGH-TEMPERATURE FLUXED PELLETS CO2 SLUDGE SLAG ferrous dust microstructure CaO conversion rate carbonated pellet green pellet
Indexed ByCSCD
Language英语
Funding Project[National Natural Science Foundation of China] ; [Natural Science Foundation of Hebei Province of China]
CSCD IDCSCD:5370021
Citation statistics
Cited Times:1[CSCD]   [CSCD Record]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/150026
Collection中国科学院金属研究所
Affiliation1.中国科学院金属研究所
2.Hebei United University, Hebei Key Lab Modern Met Technol, Tangshan 063009, Hebei, Peoples R China
Recommended Citation
GB/T 7714
Shi Yan,Liu Shimeng,Hu Changqing,et al. Microstructure Variation of Pellets Containing Ferrous Dust during Carbonation Consolidation[J]. JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL,2015,22(2):128-134.
APA Shi Yan,Liu Shimeng,Hu Changqing,&Zhang Yuzhu.(2015).Microstructure Variation of Pellets Containing Ferrous Dust during Carbonation Consolidation.JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL,22(2),128-134.
MLA Shi Yan,et al."Microstructure Variation of Pellets Containing Ferrous Dust during Carbonation Consolidation".JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL 22.2(2015):128-134.
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