| Determination of Bromine Flame Retardants in Polymers by High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry | |
| Alternative Title | Determination of Bromine Flame Retardants in Polymers by High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry |
| Fu Hui1; Li XiuQin1; Wei Chao1; Shao MingWu1; Zhang QingHe1; Li Qing2 | |
| 2013 | |
| Source Publication | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
 |
| ISSN | 0253-3820 |
| Volume | 41Issue:12Pages:1881-1886 |
| Abstract | A study was performed to determine decabromodiphenyl ether (BDE209), decabromobiphenyl (BB209) and hexabromobenzene(HBB) in polymers by high performance liquid chromatography-inductively coupled plasma mass spectrometry(HPLC-ICP-MS). Agilent TC-C-18 column(250 mmx4.6 mm, 5 mu m) was used with isopropanol/methanol/water (60: 30: 10, V/V) as mobile phase at flow rate of 0.8 mL/min. Samples were extracted with toluene, using ultrasonic-assisted extraction(UAE), and then precipitated by isooctane and methanol. Chromatographic separation and mass spectrometric conditions were optimized, and matrix effect of polystyrene (PS), acrylonitrile-butadiene-styrene copolymer (ABS) and polyethylene (PE) were evaluated. The calibration curve was linear within the range from 0.25 mg/L to 10 mg/L with a correlation coefficient of 0.9999. The recoveries of addition standard were in the range of 75.9%-103.8%. The LOD (S/N = 3) and the LOQ (S/N = 10) were within the range of 0.097-0.1 mg/L and 0.243-0.250 mg/L. The matrix inhibitions of HBB, BB209 and BDE209 in PE, ABS and PS were 25%, 10% and 3%, respectively. The results proved that the method is simple, selective, specific and suitable for determination of bromine flame retardants in polymers. |
| Keyword | POLYBROMINATED DIPHENYL ETHERS GAS-CHROMATOGRAPHY ASSISTED EXTRACTION BIPHENYLS High-Performance liquid chromatography-inductively coupled plasma mass spectrometry Bromine flame retardants Polymers |
| Indexed By | CSCD |
| Language | 英语 |
| CSCD ID | CSCD:5017970 |
| Citation statistics |
Cited Times:4[CSCD]
[CSCD Record]
|
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/151140 |
| Collection | 中国科学院金属研究所 |
| Affiliation | 1.Natl Institute Metrol, Beijing 100013, Peoples R China 2.中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | Fu Hui,Li XiuQin,Wei Chao,et al. Determination of Bromine Flame Retardants in Polymers by High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2013,41(12):1881-1886. |
| APA | Fu Hui,Li XiuQin,Wei Chao,Shao MingWu,Zhang QingHe,&Li Qing.(2013).Determination of Bromine Flame Retardants in Polymers by High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,41(12),1881-1886. |
| MLA | Fu Hui,et al."Determination of Bromine Flame Retardants in Polymers by High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 41.12(2013):1881-1886. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment