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Synthesis, Structure and Electrochemical Properties of Sulfonylcalix4 arene Supported Co-16 Cluster
Alternative TitleSynthesis,Structure and Electrochemical Properties of Sulfonylcalix4arene Supported Co_(16) Cluster
Zhang Min1; Chen Mengwei1; Gao Hong2; Bi Yanfeng1
2019
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume40Issue:10Pages:2052-2058
AbstractA new sulfonylcalix4arene-supported tetrahedral Co-16 cage cluster Co-16(TC4A-SO2)(4)(OH)(4)center dot(L)(8)(C8H20N)(C4H12N)(2)(C2H8N)center dot solvent(Abbr. Co-16-TC4A-SO2) was synthesized from CoCl2 center dot 6H(2)O, p-tert-butylsulfonylcalix4arene(H(4)TC4A-SO2) and asymmetric 3-(1H-tetrazol-5-yl)benzoic acid(H2L) under solvothermal condition. The complex was characterized by single crystal X-ray diffraction(XRD), powder X-ray diffraction(PXRD), thermogravimetric analysis(TGA), and infrared spectroscopy(FTIR). Directly loading Co-16-TC4A-SO2 onto carbon paper(Co-16-TC4A-SO2/CP) as a working electrode exhibited efficient oxygen evolution reaction(OER) catalytic performance. In 1 mol/L KOH, Co-16-TC4A-SO2/CP gained a current density of 10.0 mA/cm(2) at a catalytic reaction overpotential of 343.8 mV, a Tafel slope of 79.31 mV/dec, and catalytic stability for 48 h at 20.0 mA/cm(2).
KeywordOXYGEN EVOLUTION REACTION METAL-ORGANIC-FRAMEWORKS COORDINATION CAGE CO-II OXIDATION ELECTROCATALYSTS NI Sulfonylcalix4 arene Tetrahedral coordination cage Electrocatalytic oxygen evolution reaction
Indexed ByCSCD
Language英语
Funding Project[Fundamental Research Project of Key Lab of Educational Bureau of Liaoning Province, China] ; [Liaoning Revitalization Talents Program, China]
CSCD IDCSCD:6585951
Citation statistics
Cited Times:1[CSCD]   [CSCD Record]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/156058
Collection中国科学院金属研究所
Affiliation1.辽宁石油化工大学
2.中国科学院金属研究所
Recommended Citation
GB/T 7714
Zhang Min,Chen Mengwei,Gao Hong,et al. Synthesis, Structure and Electrochemical Properties of Sulfonylcalix4 arene Supported Co-16 Cluster[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2019,40(10):2052-2058.
APA Zhang Min,Chen Mengwei,Gao Hong,&Bi Yanfeng.(2019).Synthesis, Structure and Electrochemical Properties of Sulfonylcalix4 arene Supported Co-16 Cluster.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,40(10),2052-2058.
MLA Zhang Min,et al."Synthesis, Structure and Electrochemical Properties of Sulfonylcalix4 arene Supported Co-16 Cluster".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 40.10(2019):2052-2058.
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