Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster

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	Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster
其他题名	Formation of Two-dimensional Metal-water Framework Containing (H_2O)_(20) Cluster
	Sun YaGuang 1; Ding Fu 2; Gu XiaoFu 1; Zhang WanZhong 1; Wei DeZhou 3; Gao EnJun 1
	2008
发表期刊	CHINESE JOURNAL OF CHEMISTRY
ISSN	1001-604X
卷号	26 期号:10 页码:1843-1847
摘要	Cd(phen)(2)(male)(H2O)center dot 9.5H(2)O (1) has been synthesized by the reaction of Cd(NO3)(2) with phen and male (phen = 1,10-phenanthroline, H(2)male = maleic acid) in a mixture solvent of ethanol and distilled water. The complex was characterized by elemental analysis, infrared spectrum and thermal gravimetric analyses. The crystal structure was determined by X-ray single-crystal diffraction. In 1, a novel 1D water chain containing water (H2O)(20) cluster was formed. Further hydrogen bonding interaction between the water chain and Cd(phen)(2)(male)(H2O) constructs a unique metal-water 2D framework.
其他摘要	Cd(phen)_2(male)(H_2O)·9.5H_2O (1) has been synthesized by the reaction of Cd(NO_3)_2 with phen and male (phen=1,10-phenanthroline, H_2male=maleic acid) in a mixture solvent of ethanol and distilled water. The complex was characterized by elemental analysis, infrared spectrum and thermal gravimetric analyses. The crystal structure was determined by X-ray single-crystal diffraction. In 1, a novel 1D water chain containing water (H_2O)_20 cluster was formed. Further hydrogen bonding interaction between the water chain and Cd(phen)_2(male)(H_2O) constructs a unique metal-water 2D framework.
关键词	GRAPH-SET ANALYSIS SUPRAMOLECULAR COMPLEX HEXAMER ICE CRYSTAL CHAIN MORPHOLOGY MOLECULES CHEMISTRY PATTERNS water chemistry supramolecular self-assembly
收录类别	CSCD
语种	英语
资助项目	[National Natural Science Foundation of China] ; [Doctor Foundation of Liaoning Province]
CSCD记录号	CSCD:3434844
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/156104
专题	中国科学院金属研究所
作者单位	1.中国科学院金属研究所 2.University Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium 3.东北大学
推荐引用方式 GB/T 7714	Sun YaGuang,Ding Fu,Gu XiaoFu,et al. Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(10):1843-1847.
APA	Sun YaGuang,Ding Fu,Gu XiaoFu,Zhang WanZhong,Wei DeZhou,&Gao EnJun.(2008).Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster.CHINESE JOURNAL OF CHEMISTRY,26(10),1843-1847.
MLA	Sun YaGuang,et al."Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster".CHINESE JOURNAL OF CHEMISTRY 26.10(2008):1843-1847.