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Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)
Alternative TitleSynthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H_2O_n
EnJun Gao; XiaoFu Gu; YaGuang Sun; HongXi Yin; Qiong Wu; Lei Liu; MingChang Zhu; WanZhong Zhang
2008
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume26Issue:11Pages:2133-2136
AbstractA novel coordination polymer, Mn(PDC)H2O(n) (1) (H2PDC=pyridine-2,3-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed, and further assembled into a three-dimensional supramolecular Structure bridged by PDC ligands. Moreover, the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(II) centers within the chains and even weak ferromagnetic interactions between the Mn(II) centers in different chains.
Other AbstractA novel coordination polymer,Mn(PDC)H_2O_n(1)(H_2PDC=pyridine-2,3-dicarboxylic acid),has been hydrothermally synthesized and characterized by elemental analysis,IR and single crystal X-ray diffraction.X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed,and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands.Moreover,the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(Ⅱ)centers within the chains and even weak ferromagnetic interactions between the Mn(Ⅱ)centers in different chains.
KeywordCOORDINATION POLYMERS manganese(II) coordination polymer crystal structure magnetic property
Indexed ByCSCD
Language英语
Funding Project[Natural Science Foundation of Liaoning Province] ; [Educational Department Foundation of Liaoning Province]
CSCD IDCSCD:3585784
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/156119
Collection中国科学院金属研究所
Affiliation中国科学院金属研究所
Recommended Citation
GB/T 7714
EnJun Gao,XiaoFu Gu,YaGuang Sun,et al. Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(11):2133-2136.
APA EnJun Gao.,XiaoFu Gu.,YaGuang Sun.,HongXi Yin.,Qiong Wu.,...&WanZhong Zhang.(2008).Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n).CHINESE JOURNAL OF CHEMISTRY,26(11),2133-2136.
MLA EnJun Gao,et al."Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)".CHINESE JOURNAL OF CHEMISTRY 26.11(2008):2133-2136.
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