Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n

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	Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n
其他题名	Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n
	SUN YaGuang; RONG ShuTing; WU YongLi; YU Wan; WANG ChuanSheng; ZHANO WanZhong; GAO EnJun
	2009
发表期刊	结构化学
ISSN	0254-5861
卷号	28.0 期号:009 页码:1131-1135
摘要	The 1-D chain coordination complex of {Mn2（HCAM）3（H2bipy）·5H2O}n （H3CAM = 4-hydroxypyridine-2,6-dicarboxylic acid, bipy = 4,4＇-bipyridine） has been synthesized by the reaction of 4-hydroxypyridine-2,6-dicarboxylic acid, 4,4＇-bipyridine and manganese carbonate under hydrothermal conditions, and its crystal structure was determined by X-ray diffraction method The crystal belongs to the monoclinic system, space group P21/n with a = 10.110（2）, b = 20.159（4）, c = 17.861（4）A,β = 99.67（3）°, V = 3.5884（12） nm3, Mr= 901.47, Z = 4, Dc= 1.669 g.cm^-3, μ= 0.798 mm^-1, F（000） = 1840, the final R = 0.0713 and ωR = 0.1853. The complex forms a 1-D chain bridged by HCAM, protonated 4,4-bipyridines link the 1-D chains to construct 2-D networks via N-H...O hydrogen bonds, and networks are further extended via π-π stacking and hydrogen bonds into 3-D supramolecular framework.
其他摘要	The 1-D chain coordination complex of {Mn2（HCAM）3（H2bipy）·5H2O}n （H3CAM = 4-hydroxypyridine-2,6-dicarboxylic acid, bipy = 4,4＇-bipyridine） has been synthesized by the reaction of 4-hydroxypyridine-2,6-dicarboxylic acid, 4,4＇-bipyridine and manganese carbonate under hydrothermal conditions, and its crystal structure was determined by X-ray diffraction method The crystal belongs to the monoclinic system, space group P21/n with a = 10.110（2）, b = 20.159（4）, c = 17.861（4）A,β = 99.67（3）°, V = 3.5884（12） nm3, Mr= 901.47, Z = 4, Dc= 1.669 g.cm^-3, μ= 0.798 mm^-1, F（000） = 1840, the final R = 0.0713 and ωR = 0.1853. The complex forms a 1-D chain bridged by HCAM, protonated 4,4-bipyridines link the 1-D chains to construct 2-D networks via N-H...O hydrogen bonds, and networks are further extended via π-π stacking and hydrogen bonds into 3-D supramolecular framework.
关键词	晶体结构一维链配合物合成锰协调 X射线衍射法联吡啶
收录类别	CSCD
语种	中文
CSCD记录号	CSCD:3668506
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/157193
专题	中国科学院金属研究所
作者单位	中国科学院金属研究所
推荐引用方式 GB/T 7714	SUN YaGuang,RONG ShuTing,WU YongLi,等. Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n[J]. 结构化学,2009,28.0(009):1131-1135.
APA	SUN YaGuang.,RONG ShuTing.,WU YongLi.,YU Wan.,WANG ChuanSheng.,...&GAO EnJun.(2009).Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n.结构化学,28.0(009),1131-1135.
MLA	SUN YaGuang,et al."Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n".结构化学 28.0.009(2009):1131-1135.