| A novel hydride generation system for the simultaneous determination of lead and cadmium using atomic fluorescence Spectrometry | |
| Alternative Title | A Novel Hydride Generation System for the Simultaneous Determination of Lead and Cadmium Using Atomic Fluorescence Spectrometry |
| Zou AiMei; Yong Liu; Chen MingLi; Wang JianHua | |
| 2008 | |
| Source Publication | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
 |
| ISSN | 0253-3820 |
| Volume | 36Issue:2Pages:162-166 |
| Abstract | A novel hydride generation system was developed for the simultaneous hydride generation of lead and cadmium, i.e., the system of K3Fe(CN)(6)-(NH4)(2)Ce(NO3)(6)-NaBH4-HCl, which no interfering effects from the hydride generation of the two species were identified. The mechanisms of the hydride generation process include the oxidation of Pb(II) by (NH4)(2)Ce(NO3)(6), meanwhile, the K3Fe(CN)(6) was used as a coordinating reagent to form a complex with Pb( W) which facilitates its ensuing hydride generation. Cadmium hydride generation follows the conventional process with (NH4)(2) Ce ( NO3)(6) serves as a sensitizer. A sequential injection-hydride generation-atomic fluorescence spectrometric procedure was developed for the simultaneous determination of lead and cadmium. When employing the following experimental parameters, i.e., 2% NaBH4-3% HCl -0. 6% K3Fe(CN)(6)-0.3% (NH4)(2)Ce(NO3)(6), a 500-mu L sampling volume at a flow rate of 125 mu L/s, the obtained linear ranges were 0.4-15 mu g/L (Pb) and 0.5-20 mu g/L (Cd) respectively, along with limits of detection of 0.09 mu g/L ( Pb)and 0.17 mu g/L (Cd). The RSDs of the procedure were derived as 0. 5 % (6. 0 mu g/L Pb, n = 9) and 1. 0 % (6. 0 mu g/L Cd, n = 9). The present procedure was applied for the determination of lead and cadmium in a certified reference material of water sample, GBW08608, a coastal sea water and a riverine water sample, with satisfactory spiking recoveries. |
| Keyword | CHINESE MEDICINAL HERBS SOLID-PHASE EXTRACTION ABSORPTION-SPECTROMETRY TRACE CADMIUM SAMPLES hydride generation-atomic fluorescence spectrometry lead cadmium |
| Indexed By | CSCD |
| Language | 英语 |
| CSCD ID | CSCD:3207217 |
| Citation statistics |
Cited Times:13[CSCD]
[CSCD Record]
|
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/157366 |
| Collection | 中国科学院金属研究所 |
| Affiliation | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | Zou AiMei,Yong Liu,Chen MingLi,et al. A novel hydride generation system for the simultaneous determination of lead and cadmium using atomic fluorescence Spectrometry[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2008,36(2):162-166. |
| APA | Zou AiMei,Yong Liu,Chen MingLi,&Wang JianHua.(2008).A novel hydride generation system for the simultaneous determination of lead and cadmium using atomic fluorescence Spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,36(2),162-166. |
| MLA | Zou AiMei,et al."A novel hydride generation system for the simultaneous determination of lead and cadmium using atomic fluorescence Spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 36.2(2008):162-166. |
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