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Highly efficient Co3O4/CeO2 heterostructure as anode for lithium-ion batteries
Kang, Ying1; Zhang, Yu-Hang1; Shi, Qi2; Shi, Hongwei3; Xue, Dongfeng4; Shi, Fa-Nian1
Corresponding AuthorZhang, Yu-Hang(zhangyh@sut.edu.cn) ; Shi, Qi(shiqi594@163.com) ; Xue, Dongfeng(Dongfeng.Xue@sdu.edu.cn) ; Shi, Fa-Nian(shifn@sut.edu.cn)
2021-03-01
Source PublicationJOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN0021-9797
Volume585Pages:705-715
AbstractCo3O4 has been extensively studied as an anode material for lithium-ion batteries (LIBs) because of its high theoretical capacity. However, during the charging-discharging processes, the issues of large volume change and low electric conductivity arise, which significantly limit the practical applications of Co3O4. To solve these issues, a Co3O4/CeO2 heterostructure derived from metal-organic frameworks (MOFs) was designed and synthesized through one-step microwave synthesis. Benefiting from the mesoporous structure and presence of hetero-components, Co3O4/CeO2 having the molar ratio of Co/Ce = 5:1 (denoted as 5Co(3)O(4)/CeO2) exhibits high reversible capacity and excellent cycling stability when used as an anode material for LIBs. Specifically, compared to a single-phase Co3O4 anode, which shows a capacity of 538.6 mAh/g after 100 cycles, 5Co(3)O(4)/CeO2 exhibits a higher capacity (1131.2 mAh/g at 100 mA/g). This study provides a novel strategy for using rare earth components to modify electrode materials. (C) 2020 Elsevier Inc. All rights reserved.
KeywordCo3O4/CeO2 heterostructure One-step microwave strategy Metal-organic framework Anode Lithium-ion battery
Funding OrganizationNational Natural Science Foundation of China ; Department of Education of Liaoning Province, China
DOI10.1016/j.jcis.2020.10.050
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[21571132] ; National Natural Science Foundation of China[21822808] ; Department of Education of Liaoning Province, China[LZGD2017002]
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000604437200002
PublisherACADEMIC PRESS INC ELSEVIER SCIENCE
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/158872
Collection中国科学院金属研究所
Corresponding AuthorZhang, Yu-Hang; Shi, Qi; Xue, Dongfeng; Shi, Fa-Nian
Affiliation1.Shenyang Univ Technol, Sch Environm & Chem Engn, Shenyang 110870, Peoples R China
2.Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China
3.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
4.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
Recommended Citation
GB/T 7714
Kang, Ying,Zhang, Yu-Hang,Shi, Qi,et al. Highly efficient Co3O4/CeO2 heterostructure as anode for lithium-ion batteries[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2021,585:705-715.
APA Kang, Ying,Zhang, Yu-Hang,Shi, Qi,Shi, Hongwei,Xue, Dongfeng,&Shi, Fa-Nian.(2021).Highly efficient Co3O4/CeO2 heterostructure as anode for lithium-ion batteries.JOURNAL OF COLLOID AND INTERFACE SCIENCE,585,705-715.
MLA Kang, Ying,et al."Highly efficient Co3O4/CeO2 heterostructure as anode for lithium-ion batteries".JOURNAL OF COLLOID AND INTERFACE SCIENCE 585(2021):705-715.
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