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Controllable Synthesis, Diffusion Study and Catalysis of Hierarchical Zeolites
Zou Run1; Dong Xiao1; Jiao Yilai2; D'Agostino, Carmine1; Yan Wenfu3; Fan Xiaolei1
通讯作者Fan Xiaolei(xiaolei.fan@manchester.ac.uk)
2021-01-10
发表期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
卷号42期号:1页码:74-100
摘要Hierarchical zeolites refer to zeolitic materials having bi-/multi-modal interconnective pores arranged in order of certain ranks, which improve the molecular diffusion within their frameworks, and hence the performance in their applications such as adsorption and heterogeneous catalysis. Hierarchical zeolites are commonly produced via the top-down post-synthetic treatments (such as dealumination and/or desilication) of pre-synthesized zeolites (i.e. the parent zeolites) and the bottom-up synthesis-by-design methods (such as soft/ hard templating). This review presents the recent advances (mainly post 2000) in the strategies of making hierarchical zeolites, with the emphasis on the top-down approaches due to their relatively high practicality. Since hierarchical zeolites are proposed to improve intracrystalline diffusion, experimental studies of guest molecules diffusion in hierarchical zeolites are also reviewed. Additionally, catalytic applications of hierarchical zeolites, in comparison with the conventional microporous pristine zeolites, are also commented to highlight the advantages of hierarchical zeolites to improve catalysis.
关键词Hierarchical zeolite Post-synthetic treatment Diffusion Pulsed-field gradient nuclear magnetic resonance( PFG NMR) Catalysis
资助者European Union ; China Scholarship Council-The University of Manchester Joint Scholarship ; Programme of Introducing Talents of Discipline to Universities of China ; National Natural Science Foundation of China ; EPSRC New Investigator Award ; Natural Science Foundation of Liaoning Province,China ; National Key Research and Development Program of China
DOI10.7503/cjcu20200461
收录类别SCI
语种英语
资助项目European Union[872102] ; China Scholarship Council-The University of Manchester Joint Scholarship[201906740020] ; Programme of Introducing Talents of Discipline to Universities of China[B17020] ; National Natural Science Foundation of China[U1967215] ; National Natural Science Foundation of China[21835002] ; National Natural Science Foundation of China[21621001] ; EPSRC New Investigator Award[EP/S019138/1] ; Natural Science Foundation of Liaoning Province,China[2018010047-301] ; National Key Research and Development Program of China[SQ2019YFE011366]
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000607831700007
出版者HIGHER EDUCATION PRESS
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/159030
专题中国科学院金属研究所
通讯作者Fan Xiaolei
作者单位1.Univ Manchester, Sch Engn, Dept Chem Engn & Analyt Sci, Manchester M13 9PL, Lancs, England
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
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GB/T 7714
Zou Run,Dong Xiao,Jiao Yilai,et al. Controllable Synthesis, Diffusion Study and Catalysis of Hierarchical Zeolites[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2021,42(1):74-100.
APA Zou Run,Dong Xiao,Jiao Yilai,D'Agostino, Carmine,Yan Wenfu,&Fan Xiaolei.(2021).Controllable Synthesis, Diffusion Study and Catalysis of Hierarchical Zeolites.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,42(1),74-100.
MLA Zou Run,et al."Controllable Synthesis, Diffusion Study and Catalysis of Hierarchical Zeolites".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 42.1(2021):74-100.
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