Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis

doi:10.3389/fchem.2020.00482

IMR OpenIR

	Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis
	Abdulridha, Samer 1; Jiao, Yilai 1,2; Xu, Shaojun 1; Zhang, Rongxin 1; Garforth, Arthur A.1; Fan, Xiaolei 1
通讯作者	Fan, Xiaolei(xiaolei.fan@manchester.ac.uk)
	2020-06-30
发表期刊	FRONTIERS IN CHEMISTRY
ISSN	2296-2646
卷号	8 页码:13
摘要	Mesostructured zeolitic materials (MZMs) with relatively high acidity in comparison with the mesoporous siliceous MCM-41 were prepared via an efficient, mild, and simple post-synthetic treatment of Y zeolite facilitated by microwave irradiation, i.e., microwave-assisted chelation (MWAC). The disordered mesoporous aluminosilicates materials (DMASs) of MZM were created from Y zeolite in the absence of using mesoscale templates. The prepared DMASs showed the good mesoporous features with the mesopore area and volume of similar to 260 m(2) g(-1) and similar to 0.37 cm(3) g(-1), respectively, and with the mesopore sizes distributed in a range of 2-10 nm. MZMs possess a total acidity of about 0.6 mmol g(-1) and exhibited comparatively superior catalytic activity to the parent Y zeolite and MCM-41 in the vapor phase catalytic dealkylation of 1,3,5-triisopropylbenzene (TiPBz) and liquid phase catalytic aldol condensation of benzaldehyde with 1-heptanal. Although the yield loss was inevitable for preparing MZMs using the MWAC method, the preliminary economic analysis of the preparation cost of MZMs showed the promise. Additionally, a comprehensive comparison of the state-of-the-art mesoporous materials concerning their sustainable aspects was made, showing that MZMs are promising mesoporous materials for further development and functionalization for catalysis.
关键词	mesoporous materials microwave irradiation post-synthetic treatment zeolite MCM-41 catalysis
资助者	Higher Committee for Education Development in Iraq ; China Scholarship Council (CSC)
DOI	10.3389/fchem.2020.00482
收录类别	SCI
语种	英语
资助项目	Higher Committee for Education Development in Iraq ; China Scholarship Council (CSC)[201604910181]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000615285800001
出版者	FRONTIERS MEDIA SA
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159118
专题	中国科学院金属研究所
通讯作者	Fan, Xiaolei
作者单位	1.Univ Manchester, Dept Chem Engn & Analyt Sci, Sch Engn, Manchester, Lancs, England 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China
推荐引用方式 GB/T 7714	Abdulridha, Samer,Jiao, Yilai,Xu, Shaojun,et al. Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis[J]. FRONTIERS IN CHEMISTRY,2020,8:13.
APA	Abdulridha, Samer,Jiao, Yilai,Xu, Shaojun,Zhang, Rongxin,Garforth, Arthur A.,&Fan, Xiaolei.(2020).Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis.FRONTIERS IN CHEMISTRY,8,13.
MLA	Abdulridha, Samer,et al."Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis".FRONTIERS IN CHEMISTRY 8(2020):13.