A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating | |
Bai, Zeng-Guo1; Bai, Yao-Yao1; Zhang, Guang-Ping2; Wang, Si-Qi1; Zhang, Bin1 | |
Corresponding Author | Zhang, Bin(zhangb@atm.neu.edu.cn) |
2021-02-01 | |
Source Publication | PROGRESS IN ORGANIC COATINGS
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ISSN | 0300-9440 |
Volume | 151Pages:10 |
Abstract | Traditionally, an external stimulus is necessary for a self-healing superhydrophobic coating to achieve self repairing after physical or chemical damage, and this requirement seriously restricts the practical applications of such coatings. Fortunately, a superhydrophobic paint was fabricated successfully in present work. The paint was composed of lignocellulose (LC) and silica (SiO2) with hydroxyl-enriched surfaces coupled with octadecyltriethoxysilane (OTS) via hydrogen bonds, epoxy, and polyamide resin as binders. The paint can be applied to aluminum, glass, fabric, and many other substrates. The coated substrates were further modified with OTS to obtain self-healing superhydrophobic coatings. Only 4 h were needed for the coating to restore the original chemical composition and superhydrophobicity at room temperature after it was chemically damaged. The hydrogen bonds between LC/SiO2-OH and OTS-OH provided the efficient, spontaneous, and repeatable self healing capability for the coating. The coating possessed excellent chemical resistance and withstood 12 h of corrosion in strong acidic and alkaline solutions. Meanwhile, the coating demonstrated outstanding mechanical stability and maintained its superhydrophobic character after 5 h of water jetting (40 kPa). Also, the coated fabric could also be used for reutilized oil-water separation. |
Keyword | Hydrogen bonds Self-healing Superhydrophobic Mechanical stability Oil-water separation |
Funding Organization | National Natural Science Foundation of China (NSFC) |
DOI | 10.1016/j.porgcoat.2020.106104 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China (NSFC)[51671050] ; National Natural Science Foundation of China (NSFC)[51971060] |
WOS Research Area | Chemistry ; Materials Science |
WOS Subject | Chemistry, Applied ; Materials Science, Coatings & Films |
WOS ID | WOS:000613591500006 |
Publisher | ELSEVIER SCIENCE SA |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/159193 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Zhang, Bin |
Affiliation | 1.Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat, Minist Educ, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Bai, Zeng-Guo,Bai, Yao-Yao,Zhang, Guang-Ping,et al. A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating[J]. PROGRESS IN ORGANIC COATINGS,2021,151:10. |
APA | Bai, Zeng-Guo,Bai, Yao-Yao,Zhang, Guang-Ping,Wang, Si-Qi,&Zhang, Bin.(2021).A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating.PROGRESS IN ORGANIC COATINGS,151,10. |
MLA | Bai, Zeng-Guo,et al."A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating".PROGRESS IN ORGANIC COATINGS 151(2021):10. |
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