Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization

doi:10.1016/j.mcat.2021.111757

IMR OpenIR

	Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization
	Lu, Linjie 1; Zhang, Bingsen 2; Li, Hongping 1; Chao, Yanhong 3; Li, Yujun 1; Chen, Linlin 1; Li, Huaming 1; Ji, Hongbing 1,4; Wu, Peiwen 1; Zhu, Wenshuai 1
通讯作者	Zhu, Wenshuai(zhuws@ujs.edu.cn)
	2021-08-01
发表期刊	MOLECULAR CATALYSIS
ISSN	2468-8231
卷号	512 页码:8
摘要	Tuning electronic structure of metal catalysts by organic modification is an efficient strategy for domination of their catalytic performances. However, the electronic structure tuning over metal-free catalysts remains to be a challenge. In this work, an organic modification strategy with deep eutectic solvents (DES) as organic modifier over metal-free catalysts was proposed to tune the electronic structure of hexagonal boron nitride (h-BN). Detailed experiments showed that the electronic properties of h-BN was rationally tuned by the introduced DES, in which the B atoms in h-BN were positively charged. Meanwhile, the modulated electronic properties can lower the activation energy for the generation of hydroxyl radicals (center dot OH) from hydrogen peroxide (H2O2), thus leading to a promoted catalytic performance in oxidative desulfurization. This finding may pave a new strategy for tuning metal-free catalysts with highly-active catalytic performance.
关键词	Electronic structure Deep eutectic solvent Hexagonal boron nitride Organic modification Oxidative desulfurization
资助者	National Nat-ural Science Foundation of China ; Chinese Postdoctoral Science Foundation ; Natural Science Foundation of Jiangsu Province ; LiaoNing Revitalization Talents Program
DOI	10.1016/j.mcat.2021.111757
收录类别	SCI
语种	英语
资助项目	National Nat-ural Science Foundation of China[21878133] ; National Nat-ural Science Foundation of China[21908082] ; National Nat-ural Science Foundation of China[22008094] ; Chinese Postdoctoral Science Foundation[2019M651742] ; Chinese Postdoctoral Science Foundation[2019M651743] ; Natural Science Foundation of Jiangsu Province[BK20190852] ; LiaoNing Revitalization Talents Program[XLYC1807175]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000686886000001
出版者	ELSEVIER
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159262
专题	中国科学院金属研究所
通讯作者	Zhu, Wenshuai
作者单位	1.Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Jiangsu Univ, Sch Pharm, Zhenjiang 212013, Jiangsu, Peoples R China 4.Sun Yat sen Univ, Sch Chem, Fine Chem Ind Res Inst, Guangzhou 510275, Peoples R China
推荐引用方式 GB/T 7714	Lu, Linjie,Zhang, Bingsen,Li, Hongping,et al. Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization[J]. MOLECULAR CATALYSIS,2021,512:8.
APA	Lu, Linjie.,Zhang, Bingsen.,Li, Hongping.,Chao, Yanhong.,Li, Yujun.,...&Zhu, Wenshuai.(2021).Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization.MOLECULAR CATALYSIS,512,8.
MLA	Lu, Linjie,et al."Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization".MOLECULAR CATALYSIS 512(2021):8.