Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol

doi:10.1002/slct.202101673

IMR OpenIR

	Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol
	Lv, Lin 1; Wang, Yongzhao 2; Peng, Dengchao 1; Zhou, Zhiyuan 1; Shang, Jing 1; Guo, Wenyao 1; Zhang, Bingsen 2; Xin, Zhiling 1
通讯作者	Guo, Wenyao(guowenyao@shiep.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Xin, Zhiling(xinzhiling@126.com)
	2021-08-06
发表期刊	CHEMISTRYSELECT
ISSN	2365-6549
卷号	6 期号:29 页码:7384-7390
摘要	In this work, two-dimensional (2D) Co(OH)(2) nanosheets, with large surface areas and wrinkles are obtained, and used to support Pd nanoparticles (NPs) by simple impregnation method as an efficient catalyst for the oxidation of benzyl alcohol under solvent-free conditions. The resulting 1 wt.% Pd/Co(OH)(2) catalyst exhibits a high turnover frequency value of 57999 h(-1). The catalysts were characterized by SEM, TEM, AFM, XRD, BET, XPS and CO-pulse chemisorption. The results of characterizations reveal that the Pd NPs are highly dispersed on the Co(OH)(2) nanosheets. The abundant hydroxyl groups on the surface of Co(OH)(2) nanosheets promote the reduction of Pd species, resulting in a higher proportion of Pd-0 than that of Pd/AC catalyst, which further facilitates the catalytic performances.
关键词	Benzyl alcohol Layered Co(OH)(2) Oxidation Pd nanoparticles Supported catalysts
资助者	National Natural Science Foundation of China ; Liao Ning Revitalization Talents Program
DOI	10.1002/slct.202101673
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21773269] ; Liao Ning Revitalization Talents Program[XLYC1807175]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000680162200016
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159313
专题	中国科学院金属研究所
通讯作者	Guo, Wenyao; Zhang, Bingsen; Xin, Zhiling
作者单位	1.Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Lv, Lin,Wang, Yongzhao,Peng, Dengchao,et al. Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol[J]. CHEMISTRYSELECT,2021,6(29):7384-7390.
APA	Lv, Lin.,Wang, Yongzhao.,Peng, Dengchao.,Zhou, Zhiyuan.,Shang, Jing.,...&Xin, Zhiling.(2021).Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol.CHEMISTRYSELECT,6(29),7384-7390.
MLA	Lv, Lin,et al."Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol".CHEMISTRYSELECT 6.29(2021):7384-7390.