| TiO2 Nanotube Heterostructure Modified with a Metal-Organic Framework Showing Robust Stability for Photocathodic Protection | |
| Lu,Xiayu1,2; Liu,Li3; Cui,Yu4; Wang,Fuhui3 | |
| Corresponding Author | Lu,Xiayu() ; Liu,Li() |
| 2021-07-01 | |
| Source Publication | Journal of The Electrochemical Society
 |
| ISSN | 0013-4651 |
| Volume | 168Issue:7 |
| Abstract | TiO2 p-n heterojunctions modified with zeolitic imidazolate framework-67 (ZIF-67), a metal-organic framework, were successfully fabricated by a solution self-assembly method, and their photoelectrochemical and photocathodic performance was investigated. The presence of the organic ligands in ZIF-67 enabled ZIF-67-TiO2 photoanodes to exhibit excellent stable cathodic protection performance under simulated sunlight illumination compared with traditional organic or inorganic cocatalysts. ZIF-67-TiO2 photoanodes could provide 12 h of effective and stable photocathodic protection for 304 stainless steel (304SS) in 3.5 wt% NaCl solution. Experimental results revealed that the morphology of ZIF-67 cocatalysts affected the photoelectrochemical performance of ZIF-67-TiO2 photoanodes. Compared with large (～900 nm) ZIF-67-modified TiO2, small (～115 nm) ZIF-67-modified TiO2 demonstrated an upwardly shifted conduction band (CB) and faster separation and migration of photogenerated carriers. Furthermore, a photoanode made from small ZIF-67-modified TiO2 exhibited a lower photogenerated potential (?0.37 V) than the photoanodes made from large ZIF-67-modified TiO2 and TiO2, this photoanode could provide more effective photocathodic protection for 304SS. |
| Keyword | TiO2 ZIF-67 Surface modification P-n heterojunction Photocathodic protection |
| DOI | 10.1149/1945-7111/ac1496 |
| Language | en |
| WOS ID | IOP:0013-4651-168-7-ac1496 |
| Publisher | IOP Publishing |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/159437 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Lu,Xiayu; Liu,Li |
| Affiliation | 1.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China 2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, People’s Republic of China 3.Shenyang National Laboratory for Materials Science, Northeastern University, Shenyang 110819, People’s Republic of China 4.Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China |
| Recommended Citation GB/T 7714 | Lu,Xiayu,Liu,Li,Cui,Yu,et al. TiO2 Nanotube Heterostructure Modified with a Metal-Organic Framework Showing Robust Stability for Photocathodic Protection[J]. Journal of The Electrochemical Society,2021,168(7). |
| APA | Lu,Xiayu,Liu,Li,Cui,Yu,&Wang,Fuhui.(2021).TiO2 Nanotube Heterostructure Modified with a Metal-Organic Framework Showing Robust Stability for Photocathodic Protection.Journal of The Electrochemical Society,168(7). |
| MLA | Lu,Xiayu,et al."TiO2 Nanotube Heterostructure Modified with a Metal-Organic Framework Showing Robust Stability for Photocathodic Protection".Journal of The Electrochemical Society 168.7(2021). |
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