| Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy | |
| Peng, Weidan1,2; Yan, Yukun1; Zhang, Dawei1,2; Zhou, Yangtao1; Na, Duo1; Xiao, Chenjuan1,2; Yang, Chengling1; Wen, Guodong1; Zhang, Jinsong1 | |
| Corresponding Author | Zhang, Jinsong(jszhang@imr.ac.cn) |
| 2021-09-05 | |
| Source Publication | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| ISSN | 0927-7757 |
| Volume | 624Pages:9 |
| Abstract | Hydrogel is low-cost porous material that has been used as effective support for confining metal nanoparticles due to its interconnected three-dimensional (3D) networks. Cellulose gel with covalently crosslinking has good thermal stability and can be used as support to stabilize metal nanoparticles in the high temperature environment. In this work, (Cu, Pd, Au) nanoparticles were immobilized on covalently crosslinked cellulose gel via adsorption and in situ reduction, followed by pyrolysis to obtain carbon-supported metal nanoparticles. Typically, the Cu nanoparticles were highly dispersed in the gels due to the interconnected networks and functional groups that restricted the aggregation of metal nanoparticles and improved the stability of the gel framework during pyrolysis. The results were confirmed by XRD, TEM, XPS, and FT-IR analyses. Furthermore, the Cu NPs exhibited good catalytic activity and selectivity for the hydrogenation of nitroaromatics with a TOF of 6656 h(-1), which was comparable to previously reported Pd catalysts. The catalyst remained its activity after 10 recycles, demonstrating the high stability and activity of the Cu NPs prepared by this method. This work provides a green synthetic pathway for the construction of size-controlled metal nanoparticles immobilized on a carbon support. |
| Keyword | Cellulose hydrogel Covalent cross-linking structure Metal nanoparticles Nitroaromatic hydrogenation |
| Funding Organization | Liaoning Revitalization Talents Program ; SYNL |
| DOI | 10.1016/j.colsurfa.2021.126809 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Liaoning Revitalization Talents Program[XLYC1808013] ; SYNL[L2019F6] ; SYNL[L2019F15] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000660291700005 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/160610 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Zhang, Jinsong |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China |
| Recommended Citation GB/T 7714 | Peng, Weidan,Yan, Yukun,Zhang, Dawei,et al. Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2021,624:9. |
| APA | Peng, Weidan.,Yan, Yukun.,Zhang, Dawei.,Zhou, Yangtao.,Na, Duo.,...&Zhang, Jinsong.(2021).Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,624,9. |
| MLA | Peng, Weidan,et al."Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 624(2021):9. |
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