Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy

doi:10.1016/j.colsurfa.2021.126809

IMR OpenIR

	Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy
	Peng, Weidan 1,2; Yan, Yukun 1; Zhang, Dawei 1,2; Zhou, Yangtao 1; Na, Duo 1; Xiao, Chenjuan 1,2; Yang, Chengling 1; Wen, Guodong 1; Zhang, Jinsong 1
通讯作者	Zhang, Jinsong(jszhang@imr.ac.cn)
	2021-09-05
发表期刊	COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN	0927-7757
卷号	624 页码:9
摘要	Hydrogel is low-cost porous material that has been used as effective support for confining metal nanoparticles due to its interconnected three-dimensional (3D) networks. Cellulose gel with covalently crosslinking has good thermal stability and can be used as support to stabilize metal nanoparticles in the high temperature environment. In this work, (Cu, Pd, Au) nanoparticles were immobilized on covalently crosslinked cellulose gel via adsorption and in situ reduction, followed by pyrolysis to obtain carbon-supported metal nanoparticles. Typically, the Cu nanoparticles were highly dispersed in the gels due to the interconnected networks and functional groups that restricted the aggregation of metal nanoparticles and improved the stability of the gel framework during pyrolysis. The results were confirmed by XRD, TEM, XPS, and FT-IR analyses. Furthermore, the Cu NPs exhibited good catalytic activity and selectivity for the hydrogenation of nitroaromatics with a TOF of 6656 h(-1), which was comparable to previously reported Pd catalysts. The catalyst remained its activity after 10 recycles, demonstrating the high stability and activity of the Cu NPs prepared by this method. This work provides a green synthetic pathway for the construction of size-controlled metal nanoparticles immobilized on a carbon support.
关键词	Cellulose hydrogel Covalent cross-linking structure Metal nanoparticles Nitroaromatic hydrogenation
资助者	Liaoning Revitalization Talents Program ; SYNL
DOI	10.1016/j.colsurfa.2021.126809
收录类别	SCI
语种	英语
资助项目	Liaoning Revitalization Talents Program[XLYC1808013] ; SYNL[L2019F6] ; SYNL[L2019F15]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000660291700005
出版者	ELSEVIER
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/160610
专题	中国科学院金属研究所
通讯作者	Zhang, Jinsong
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Peng, Weidan,Yan, Yukun,Zhang, Dawei,et al. Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2021,624:9.
APA	Peng, Weidan.,Yan, Yukun.,Zhang, Dawei.,Zhou, Yangtao.,Na, Duo.,...&Zhang, Jinsong.(2021).Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,624,9.
MLA	Peng, Weidan,et al."Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 624(2021):9.