Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives

doi:10.1002/aenm.202100387

IMR OpenIR

	Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives
	Qi, Fulai 1; Sun, Zhenhua 1,2; Fan, Xialu 1,2; Wang, Zhenxing 1,2; Shi, Ying 1; Hu, Guangjian 1; Li, Feng 1,2,3
通讯作者	Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2021-04-15
发表期刊	ADVANCED ENERGY MATERIALS
ISSN	1614-6832
页码	25
摘要	Lithium-sulfur (Li-S) batteries, with high theoretical energy density, promise to be the optimal candidate of next-generation energy-storage. Rapid development in materials has made a major step forward in Li-S batteries. However, a big gap in cycle life and efficiency for practical applications still remains. Reasonable design of materials/electrodes a is significant aspect that must be addressed. The rising metal-organic frameworks (MOFs) are a new class of crystalline porous organic-inorganic hybrid materials. Abundant inorganic nodes and designable organic linkers allow tailored pore chemistry at a molecular-scale, which enables tunable interaction with electroactive components in Li-S batteries. In this review, the interaction between basic component/structure of MOFs and electroactive components in Li-S batteries is clarified to guide precise function-driven design of MOFs. First, the reaction mechanisms and issues in Li-S batteries are briefly summarized. Second, the structural advantages of MOFs in pore chemistry and morphology are highlighted. Based on the above two aspects of understanding, a bridge between issue-structure-function is proposed. The interaction between MOFs with transport and reaction of electroactive components are discussed. Finally, a perspective on the future development of MOFs based materials in Li-S batteries are given. It is believed that the tunable interaction will boost the frontier interdiscipline of MOFs based electrochemical systems.
关键词	electroactive components interactions lithium‐ sulfur batteries metal‐ organic frameworks
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Special Projects of the Central Government in Guidance of Local Science and Technology Development ; China Postdoctoral Science Foundation
DOI	10.1002/aenm.202100387
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; National Natural Science Foundation of China[51902316] ; National Natural Science Foundation of China[51525206] ; National Key R&D Program of China[2016YFA0200100] ; National Key R&D Program of China[2016YFB0100100] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; LiaoNing Revitalization Talents Program[XLYC1908015] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; Special Projects of the Central Government in Guidance of Local Science and Technology Development[2020JH6/10500024] ; China Postdoctoral Science Foundation[2019M651162]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000640240400001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：69[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/162069
专题	中国科学院金属研究所
通讯作者	Sun, Zhenhua; Li, Feng
作者单位	1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Shenyang Ind Technol Res Inst Energy Mat & Device, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Qi, Fulai,Sun, Zhenhua,Fan, Xialu,et al. Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives[J]. ADVANCED ENERGY MATERIALS,2021:25.
APA	Qi, Fulai.,Sun, Zhenhua.,Fan, Xialu.,Wang, Zhenxing.,Shi, Ying.,...&Li, Feng.(2021).Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives.ADVANCED ENERGY MATERIALS,25.
MLA	Qi, Fulai,et al."Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives".ADVANCED ENERGY MATERIALS (2021):25.