| Recent progress of carbon-based metal-free materials in thermal-driven catalysis | |
| Wu, Shuchang1; Yu, Linhui2; Wen, Guodong3; Xie, Zailai4; Lin, Yangming3 | |
| Corresponding Author | Wu, Shuchang(scwu10b@alum.imr.ac.cn) ; Yu, Linhui(linhui.yu@cec.mpg.de) ; Lin, Yangming(Yang-Ming.Lin@cec.mpg.de) |
| 2021-07-01 | |
| Source Publication | JOURNAL OF ENERGY CHEMISTRY
 |
| ISSN | 2095-4956 |
| Volume | 58Pages:318-335 |
| Abstract | The carbon-based metal-free materials as catalysts (named as carbocatalysts) have been attracting tremendous attentions in electric-, solar-and thermal-driven reactions nowadays. Compared to electrocatalysis and photocatalysis, the thermal-driven catalysis (thermocatalysis) including liquid phase and gas phase reactions involves wider scope and is relatively easy to realize practical large-scale applications. Over the past several years, some striking achievements on the design of new carbon-based metal-free materials with well-defined structures and heteroatom groups as well as the revelation of new reaction mechanisms and active sites in thermocatalysis have been obtained. However, comparative discussions regarding these recent achievements have been rarely highlighted. In this review, we systematically summarize and discuss six kinds of carbocatalysts and their applications in thermocatalysis. These materials include typical oxygen-attached carbon, surface modified carbon (graft with certain organic compounds), mono-doped carbon, co-doped carbon, carbon nitride and materials with carbon as dopant. Some new reaction processes as well as the related reaction mechanisms, active sites and intermediates are reviewed critically. Moreover, an outlook on the in-depth investigation of the metal free carbocatalysis in the future is provided. (c) 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. |
| Keyword | Carbocatalysis Metal-free Thermal-driven catalysis Active sites |
| Funding Organization | Award Program for Fujian Minjiang Scholar Professorship ; National Natural Science Foundation of China ; Chemical Engineering & Technology of Zhejiang Province First-Class Discipline (Taizhou University) ; Zhejiang Provincial Natural Science Foundation of China ; Taizhou science and technology planning project |
| DOI | 10.1016/j.jechem.2020.10.011 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Award Program for Fujian Minjiang Scholar Professorship ; National Natural Science Foundation of China[21571035] ; Chemical Engineering & Technology of Zhejiang Province First-Class Discipline (Taizhou University) ; Zhejiang Provincial Natural Science Foundation of China[LQ20B060001] ; Taizhou science and technology planning project[1902gy20] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000640197600001 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/162266 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Wu, Shuchang; Yu, Linhui; Lin, Yangming |
| Affiliation | 1.Taizhou Univ, Sch Pharmaceut & Mat Engn, Taizhou 318000, Zhejiang, Peoples R China 2.Max Planck Inst Chem Energy Convers, Stiftstr 34-36, D-45470 Mulheim, Germany 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 4.Fuzhou Univ, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou 350016, Peoples R China |
| Recommended Citation GB/T 7714 | Wu, Shuchang,Yu, Linhui,Wen, Guodong,et al. Recent progress of carbon-based metal-free materials in thermal-driven catalysis[J]. JOURNAL OF ENERGY CHEMISTRY,2021,58:318-335. |
| APA | Wu, Shuchang,Yu, Linhui,Wen, Guodong,Xie, Zailai,&Lin, Yangming.(2021).Recent progress of carbon-based metal-free materials in thermal-driven catalysis.JOURNAL OF ENERGY CHEMISTRY,58,318-335. |
| MLA | Wu, Shuchang,et al."Recent progress of carbon-based metal-free materials in thermal-driven catalysis".JOURNAL OF ENERGY CHEMISTRY 58(2021):318-335. |
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