| Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application | |
| Chen, Xiaowen1,2; Jia, Zhimin1,2; Huang, Fei2; Diao, Jiangyong2; Liu, Hongyang1,2 | |
| Corresponding Author | Liu, Hongyang(liuhy@imr.ac.cn) |
| 2021-11-04 | |
| Source Publication | CHEMICAL COMMUNICATIONS
 |
| ISSN | 1359-7345 |
| Volume | 57Issue:88Pages:11591-11603 |
| Abstract | Atomically dispersed metal catalysts (ADMCs) have attracted increasing interest in the field of heterogeneous catalysis. As sub-nanometric catalysts, ADMCs have exhibited remarkable catalytic performance in many reactions. ADMCs are classified into two categories: single atom catalysts (SACs) and atomically dispersed clusters with a few atoms. To stabilize the highly active ADMCs, nanodiamond (ND) and its derivatives (NDDs) are promising supports. In this Feature Article, we have introduced the advantages of NDDs with a highly curved surface and tunable surface properties. The controllable defective sites and oxygen functional groups are known as the anchoring sites for ADMCs. Tunable surface acid-base properties enable ADMCs supported on NDDs to exhibit unique selectivity towards target products and an extended lifetime in many reactions. In addition, we have firstly overviewed the recent advances in the synthesis strategies for effectively fabricating ADMCs on NDDs, and further discussed how to achieve the atomic dispersion of metal precursors and stabilize the as-formed metal atoms against migration and agglomeration based on NDDs. And then, we have also systematically summarized the advantages of ADMCs supported on NDDs in reactions, including hydrogenation, dehydrogenation, aerobic oxidation and electrochemical reaction. These reactions can also effectively guide the design of ADMCs. The recent progress in understanding the effect of structure of active centers and metal-support interactions (MSIs) on the catalytic performance of ADMCs is particularly highlighted. At last, the possible research directions in ADMCs are forecasted. |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Dalian National Lab for Clean Energy (DNL Cooperation Fund) ; Shenyang National Laboratory for Materials Science ; Sinopec China |
| DOI | 10.1039/d1cc05202k |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2016YFA0204100] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[22072162] ; Liaoning Revitalization Talents Program[XLYC1907055] ; Dalian National Lab for Clean Energy (DNL Cooperation Fund)[202001] ; Shenyang National Laboratory for Materials Science ; Sinopec China |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000708033200001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/166620 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Hongyang |
| Affiliation | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Xiaowen,Jia, Zhimin,Huang, Fei,et al. Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application[J]. CHEMICAL COMMUNICATIONS,2021,57(88):11591-11603. |
| APA | Chen, Xiaowen,Jia, Zhimin,Huang, Fei,Diao, Jiangyong,&Liu, Hongyang.(2021).Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application.CHEMICAL COMMUNICATIONS,57(88),11591-11603. |
| MLA | Chen, Xiaowen,et al."Atomically dispersed metal catalysts on nanodiamond and its derivatives: synthesis and catalytic application".CHEMICAL COMMUNICATIONS 57.88(2021):11591-11603. |
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