A neutral polysulfide/ferricyanide redox flow battery | |
Long, Yong1; Xu, Zhizhao1; Wang, Guixiang1; Xu, He1; Yang, Minghui1; Ding, Mei1,2; Yuan, Du1; Yan, Chuanwei3; Sun, Qijun4; Liu, Min5; Jia, Chuankun1 | |
Corresponding Author | Ding, Mei(dingmei@csust.edu.cn) ; Jia, Chuankun(jiachuankun@csust.edu.cn) |
2021-10-22 | |
Source Publication | ISCIENCE
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Volume | 24Issue:10Pages:13 |
Abstract | Energy storage systems are crucial in the deployment of renewable energies. As one of the most promising solutions, redox flow batteries (RFBs) are still hindered for practical applications by low energy density, high cost, and environmental concerns. To breakthrough the fundamental solubility limit that restricts boosting energy density of the cell, we here demonstrate a new RFB system employing polysulfide and high concentrated ferricyanide (up to 1.6M) species as reactants. The RFB cell exhibits high cell performances with capacity retention of 96.9% after 1,500 cycles and low reactant cost of $32.47/kWh. Moreover, neutral aqueous electrolytes are environmentally benign and cost-effective. A cell stack is assembled and exhibits low capacity fade rate of 0.021% per cycle over 642 charging-discharging steps (spans 60 days). This neutral polysulfide/ferricyanide RFB technology with high safety, long-duration, low cost, and feasibility of scale-up is an innovative design for storing massive energy. |
Funding Organization | 100 Talented Team of Hunan Province ; Huxiang high-level talents'' program ; Open Fund of National Engineering Laboratory of Highway Maintenance Technology (Changsha University of Science Technology) |
DOI | 10.1016/j.isci.2021.103157 |
Indexed By | SCI |
Language | 英语 |
Funding Project | 100 Talented Team of Hunan Province[91] ; Huxiang high-level talents'' program[2019RS1046] ; Huxiang high-level talents'' program[2018RS3077] ; Open Fund of National Engineering Laboratory of Highway Maintenance Technology (Changsha University of Science Technology)[kfj170105] |
WOS Research Area | Science & Technology - Other Topics |
WOS Subject | Multidisciplinary Sciences |
WOS ID | WOS:000713819300005 |
Publisher | CELL PRESS |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/167237 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Ding, Mei; Jia, Chuankun |
Affiliation | 1.Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China 2.Changsha Univ Sci & Technol, Natl Engn Lab Highway Maintenance Technol, Changsha 410114, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 4.Chinese Acad Sci, Univ Chinese Acad Sci, Sch Nanosci & Technol, Beijing Inst Nanoenergy & Nanosyst, Beijing 100049, Peoples R China 5.Cent South Univ, Sch Phys & Elect, Inst Super Microstruct & Ultrafast Proc Adv Mat, Changsha 410083, Peoples R China |
Recommended Citation GB/T 7714 | Long, Yong,Xu, Zhizhao,Wang, Guixiang,et al. A neutral polysulfide/ferricyanide redox flow battery[J]. ISCIENCE,2021,24(10):13. |
APA | Long, Yong.,Xu, Zhizhao.,Wang, Guixiang.,Xu, He.,Yang, Minghui.,...&Jia, Chuankun.(2021).A neutral polysulfide/ferricyanide redox flow battery.ISCIENCE,24(10),13. |
MLA | Long, Yong,et al."A neutral polysulfide/ferricyanide redox flow battery".ISCIENCE 24.10(2021):13. |
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