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Enhanced corrosion resistance by engineering crystallography on metals
Wei, X. X.1,2; Zhang, B.1; Wu, B.3; Wang, Y. J.1; Tian, X. H.1,2; Yang, L. X.1; Oguzie, E. E.4; Ma, X. L.1,5
Corresponding AuthorMa, X. L.(xlma@imr.ac.cn)
2022-02-07
Source PublicationNATURE COMMUNICATIONS
Volume13Issue:1Pages:13
AbstractPassive films on metal surfaces provide better corrosion resistance, but they can degrade in long-term service. Here the authors demonstrate a strategy to engineer crystallographic configuration at the metal/film interface to further improve corrosion resistance. Nanometer-thick passive films, which impart superior corrosion resistance to metals, are degraded in long-term service; they are also susceptible to chloride-induced localized attack. Here we show, by engineering crystallographic configurations upon metal matrices adjacent to their passive films, we obtain great enhancement of corrosion resistance of FeCr15Ni15 single crystal in sulphuric acid, with activation time up to two orders of magnitude longer than that of the non-engineered counterparts. Meanwhile, engineering crystallography decreases the passive current density and shifts the pitting potential to noble values. Applying anodic polarizations under a transpassivation potential, we make the metal matrices underneath the transpassive films highly uneven with {111}-terminated configurations, which is responsible for the enhancement of corrosion resistance. The transpassivation strategy also works in the commercial stainless steels where both grain interior and grain boundaries are rebuilt into the low-energy configurations. Our results demonstrate a technological implication in the pretreatment process of anti-corrosion engineering.
Funding OrganizationNational Natural Science Foundation of China ; Key Research Program of Frontier Sciences CAS ; World Bank
DOI10.1038/s41467-022-28368-8
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[51971228] ; National Natural Science Foundation of China[51771212] ; Key Research Program of Frontier Sciences CAS[QYZDJ-SSW-JSC010] ; World Bank
WOS Research AreaScience & Technology - Other Topics
WOS SubjectMultidisciplinary Sciences
WOS IDWOS:000752524300004
PublisherNATURE PORTFOLIO
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/173433
Collection中国科学院金属研究所
Corresponding AuthorMa, X. L.
Affiliation1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
3.Bay Area Ctr Electron Microscopy, Songshan Lake Mat Lab, Dongguan 523808, Guangdong, Peoples R China
4.Fed Univ Technol Owerri, Africa Ctr Excellence Future Energies & Electroch, PMB 1526, Owerri, Imo State, Nigeria
5.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
Recommended Citation
GB/T 7714
Wei, X. X.,Zhang, B.,Wu, B.,et al. Enhanced corrosion resistance by engineering crystallography on metals[J]. NATURE COMMUNICATIONS,2022,13(1):13.
APA Wei, X. X..,Zhang, B..,Wu, B..,Wang, Y. J..,Tian, X. H..,...&Ma, X. L..(2022).Enhanced corrosion resistance by engineering crystallography on metals.NATURE COMMUNICATIONS,13(1),13.
MLA Wei, X. X.,et al."Enhanced corrosion resistance by engineering crystallography on metals".NATURE COMMUNICATIONS 13.1(2022):13.
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