Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics

doi:10.1016/j.jcis.2021.10.105

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	Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics
	Wu, Genghuang 1; Zhao, Linmin 2,3; Zong, Mingsheng 1; Yu, Peng 1; Xie, Jingxin 1; Da, Zhijian 1; Liu, Hongyang 2,3; Rong, Junfeng 1
通讯作者	Da, Zhijian(dazhijian.ripp@sinopec.com) ; Liu, Hongyang(liuhy@imr.ac.cn) ; Rong, Junfeng(rongjf.ripp@sinopec.com)
	2022-02-15
发表期刊	JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN	0021-9797
卷号	608 页码:1278-1285
摘要	Graphene encapsulating 3d transition metal nanoparticles (Ni, Co, Fe@G) are successfully fabricated through pyrolysis of complexes which are simply prepared via "acid-base reactions" between metal hydroxides and carboxylic acid such as citric acid. In particular, the Ni@G catalyst exhibits outstanding catalytic activity and selectivity (>99%) toward the reduction of various nitroaromatics under mild conditions (1 MPa H-2, 60 degrees C), even in the presence of poisons (CO and thiophene etc.). This "acid-base reactions" based method provides a facile and scalable approach to prepare graphene encapsulating 3d transition metals with wide ranges of applications. (C) 2021 Elsevier Inc. All rights reserved.
关键词	Graphene encapsulation 3d transition metal nanoparticles Chemoselective hydrogenation Anti-poisoning Nitroarenes
资助者	China Petrochemical Corporation ; National Key R&D Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Dalian National Lab for Clean Energy, (DNL Cooperation Fund)
DOI	10.1016/j.jcis.2021.10.105
收录类别	SCI
语种	英语
资助项目	China Petrochemical Corporation[420043-4] ; China Petrochemical Corporation[420043-10] ; National Key R&D Program of China[2016YFA0204100] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[22072162] ; Liaoning Revitalization Talents Program[XLYC1907055] ; Dalian National Lab for Clean Energy, (DNL Cooperation Fund)[202001]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000744111100007
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/173627
专题	中国科学院金属研究所
通讯作者	Da, Zhijian; Liu, Hongyang; Rong, Junfeng
作者单位	1.SINOPEC, Res Inst Petr Proc, Beijing 100083, Peoples R China 2.Chinese Acad Sci Inst, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Wu, Genghuang,Zhao, Linmin,Zong, Mingsheng,et al. Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2022,608:1278-1285.
APA	Wu, Genghuang.,Zhao, Linmin.,Zong, Mingsheng.,Yu, Peng.,Xie, Jingxin.,...&Rong, Junfeng.(2022).Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics.JOURNAL OF COLLOID AND INTERFACE SCIENCE,608,1278-1285.
MLA	Wu, Genghuang,et al."Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics".JOURNAL OF COLLOID AND INTERFACE SCIENCE 608(2022):1278-1285.