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Electron emission mechanism of scandium-tungsten cathodes
Cheng, Yin1,2; Sun, Yuan1; Zhou, Yizhou1; Wang, Shiyang1; Meng, Jie1
通讯作者Sun, Yuan(yuansun@imr.ac.cn) ; Zhou, Yizhou(yzzhou@imr.ac.cn)
2022-06-01
发表期刊INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
ISSN0263-4368
卷号105页码:5
摘要Scandium-tungsten (Sc-W) cathodes have garnered a lot of research attention due to their high emission current density. This study investigates the electronic properties of Sc-W cathodes using the VASP code to explain the operating mechanism of hot electron emission. The results reveal that the work function is decreased by 0.58 eV, whereas the charge density in the crystal structure, the number of high valence electrons and the energy of electrons increase when Sc content is increased from 1% to 2%. Moreover, the bandgap and energy required for electrons to jump from the valence band to the conduction band decreased with the increase of Sc content, enhancing the current emission density and reducing the work function of the cathode.
关键词Thermoelectric materials Crystal structure Electronic structure Density functional theory First-principle calculations
资助者National Science and Technology Major Project ; Key Specialized Research and Development Breakthrough - unveiling and Commanding the Special Project Program in Liaoning Province
DOI10.1016/j.ijrmhm.2022.105828
收录类别SCI
语种英语
资助项目National Science and Technology Major Project[J2019-VI-0018-0133] ; Key Specialized Research and Development Breakthrough - unveiling and Commanding the Special Project Program in Liaoning Province[2021JH15]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000793482500002
出版者ELSEVIER SCI LTD
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/173891
专题中国科学院金属研究所
通讯作者Sun, Yuan; Zhou, Yizhou
作者单位1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Yin,Sun, Yuan,Zhou, Yizhou,et al. Electron emission mechanism of scandium-tungsten cathodes[J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS,2022,105:5.
APA Cheng, Yin,Sun, Yuan,Zhou, Yizhou,Wang, Shiyang,&Meng, Jie.(2022).Electron emission mechanism of scandium-tungsten cathodes.INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS,105,5.
MLA Cheng, Yin,et al."Electron emission mechanism of scandium-tungsten cathodes".INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS 105(2022):5.
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