Electron emission mechanism of scandium-tungsten cathodes | |
Cheng, Yin1,2; Sun, Yuan1; Zhou, Yizhou1; Wang, Shiyang1; Meng, Jie1 | |
通讯作者 | Sun, Yuan(yuansun@imr.ac.cn) ; Zhou, Yizhou(yzzhou@imr.ac.cn) |
2022-06-01 | |
发表期刊 | INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
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ISSN | 0263-4368 |
卷号 | 105页码:5 |
摘要 | Scandium-tungsten (Sc-W) cathodes have garnered a lot of research attention due to their high emission current density. This study investigates the electronic properties of Sc-W cathodes using the VASP code to explain the operating mechanism of hot electron emission. The results reveal that the work function is decreased by 0.58 eV, whereas the charge density in the crystal structure, the number of high valence electrons and the energy of electrons increase when Sc content is increased from 1% to 2%. Moreover, the bandgap and energy required for electrons to jump from the valence band to the conduction band decreased with the increase of Sc content, enhancing the current emission density and reducing the work function of the cathode. |
关键词 | Thermoelectric materials Crystal structure Electronic structure Density functional theory First-principle calculations |
资助者 | National Science and Technology Major Project ; Key Specialized Research and Development Breakthrough - unveiling and Commanding the Special Project Program in Liaoning Province |
DOI | 10.1016/j.ijrmhm.2022.105828 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Science and Technology Major Project[J2019-VI-0018-0133] ; Key Specialized Research and Development Breakthrough - unveiling and Commanding the Special Project Program in Liaoning Province[2021JH15] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000793482500002 |
出版者 | ELSEVIER SCI LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/173891 |
专题 | 中国科学院金属研究所 |
通讯作者 | Sun, Yuan; Zhou, Yizhou |
作者单位 | 1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Cheng, Yin,Sun, Yuan,Zhou, Yizhou,et al. Electron emission mechanism of scandium-tungsten cathodes[J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS,2022,105:5. |
APA | Cheng, Yin,Sun, Yuan,Zhou, Yizhou,Wang, Shiyang,&Meng, Jie.(2022).Electron emission mechanism of scandium-tungsten cathodes.INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS,105,5. |
MLA | Cheng, Yin,et al."Electron emission mechanism of scandium-tungsten cathodes".INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS 105(2022):5. |
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