| Superior electrochemcial performances of core-shell structured vanadium oxide@vanadium carbide composites for Li-ion storage | |
| Liu, Rui Jia1,2; Yang, Ling Xu3; Lin, Guang Qiang3; Bu, Huan Peng3; Wang, Wen Jun3; Liu, Hui Jun3; Zeng, Chao Liu3 | |
| Corresponding Author | Liu, Hui Jun(hui_jun_liu@163.com) ; Zeng, Chao Liu(clzeng@imr.ac.cn) |
| 2022-06-30 | |
| Source Publication | APPLIED SURFACE SCIENCE
 |
| ISSN | 0169-4332 |
| Volume | 588Pages:11 |
| Abstract | Vanadium oxide@vanadium carbide (VxOy@VxC) composites with a core-shell structure was constructed via a simple in-situ oxidation method, i.e. by oxidizing V2C precursor at 350-400 degrees C for 1 h under air atmosphere. As obtained VxOy@VxC composites are in the submicro-sized particle distribution. These VxOy@VxC composites have displayed remarkable electrochemical performances as anodes in lithium-ion batteries (LIBs), thereinto V2O5@VO2@V2C@VC composite exhibits the most impressive cycling stability, releasing-252.1 mAh g(-1) after 200 cycles at 0.5 A g(-1) with capacity retention of 89.5% and-492 mAh g(-1) in the continuous 120 cycles at 0.1 A g(-1). Such an outstanding electrochemical performance could benefit from the unique core-shell heterostructure of VxC encapsulated by VxOy, with an excellent structural stability. It is favorable to provide the excellent charge transfer field and effectively restrain the aggregation and structural deformation during the electrochemical reaction process. This design of V2O5@VO2@V2C@VC composite is promising for motivating the development of anode materials in LIBs. |
| Keyword | Vanadium carbide Vanadium oxide Lithium-ion batteries Anode Composite Heterostructure |
| Funding Organization | National Natural Science Foundation of China |
| DOI | 10.1016/j.apsusc.2022.152904 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51671204] |
| WOS Research Area | Chemistry ; Materials Science ; Physics |
| WOS Subject | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
| WOS ID | WOS:000791555000002 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/173951 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Hui Jun; Zeng, Chao Liu |
| Affiliation | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Rui Jia,Yang, Ling Xu,Lin, Guang Qiang,et al. Superior electrochemcial performances of core-shell structured vanadium oxide@vanadium carbide composites for Li-ion storage[J]. APPLIED SURFACE SCIENCE,2022,588:11. |
| APA | Liu, Rui Jia.,Yang, Ling Xu.,Lin, Guang Qiang.,Bu, Huan Peng.,Wang, Wen Jun.,...&Zeng, Chao Liu.(2022).Superior electrochemcial performances of core-shell structured vanadium oxide@vanadium carbide composites for Li-ion storage.APPLIED SURFACE SCIENCE,588,11. |
| MLA | Liu, Rui Jia,et al."Superior electrochemcial performances of core-shell structured vanadium oxide@vanadium carbide composites for Li-ion storage".APPLIED SURFACE SCIENCE 588(2022):11. |
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