An Interlayer Containing Dissociated LiNO3 with Fast Release Speed for Stable Lithium Metal Batteries with 400 Wh kg(-1) Energy Density

doi:10.1002/smll.202202349

IMR OpenIR

	An Interlayer Containing Dissociated LiNO3 with Fast Release Speed for Stable Lithium Metal Batteries with 400 Wh kg(-1) Energy Density
	Yang, Huicong 1,2; Liu, Qingyun 1,2; Wang, Yaozu 1,2; Ma, Zhuoting 1,3; Tang, Pei 1,2; Zhang, Xiaoyin 1,2; Cheng, Hui-Ming 1,4; Sun, Zhenhua 1,2; Li, Feng 1,2,5
通讯作者	Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2022-05-26
发表期刊	SMALL
ISSN	1613-6810
页码	9
摘要	Lithium metal is an ideal electrode material for future rechargeable batteries. However, dendrite formation and unstable solid electrolyte interphase film lead to safety concerns and poor Coulombic efficiency (CE). LiNO3 significantly improves the performance of the lithium metal anode in ester electrolytes but its use is restricted by low solubility. To increase the content of LiNO3 in the cell, a poly-(vinyl carbonate) organogel interlayer containing dissociated LiNO3 (LNO-PVC) is placed between the cathode and anode. The dissociated LiNO3 effectively increases the LiNO3-release rate and compensates for the LiNO3 consumed in ester electrolytes during cycling. Via this interlayer, the performance of the lithium metal anode is significantly improved. The average CE of a Li-Cu cell reaches 98.6% at 0.5 mA cm(-2)-1 h and 98.5% at 1 mA cm(-2)-1 h for 300 cycles. Also, a Li\|\|NCM811 pouch cell with LNO-PVC interlayer can also reach a 400 Wh kg(-1) energy density with a cycling life of 65 cycles. This strategy sheds light on the effect of the state of this salt on its release/dissolution kinetics, which is determined by the interactions between the salt and host material.
关键词	carbonate electrolyte dissociated state of LiNO (3) fast release rate lithium metal anode interlayer
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Liaoning Revitalization Talents Program ; DNL Cooperation Fund, CAS
DOI	10.1002/smll.202202349
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52188101] ; National Key R&D Program of China[2016YFA0200102] ; National Key R&D Program of China[2016YFB0100100] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; Liaoning Revitalization Talents Program[XLYC1908015] ; Liaoning Revitalization Talents Program[XLYC2007080] ; DNL Cooperation Fund, CAS[DNL202019]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000802048900001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174117
专题	中国科学院金属研究所
通讯作者	Sun, Zhenhua; Li, Feng
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.China Med Univ, Coll Life Sci, Dept Biochem & Mol Biol, Shenyang 110122, Peoples R China 4.Chinese Acad Sci, Shenzhen Inst Adv Technol, Inst Technol Carbon Neutral, Shenzhen 518055, Peoples R China 5.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Yang, Huicong,Liu, Qingyun,Wang, Yaozu,et al. An Interlayer Containing Dissociated LiNO3 with Fast Release Speed for Stable Lithium Metal Batteries with 400 Wh kg(-1) Energy Density[J]. SMALL,2022:9.
APA	Yang, Huicong.,Liu, Qingyun.,Wang, Yaozu.,Ma, Zhuoting.,Tang, Pei.,...&Li, Feng.(2022).An Interlayer Containing Dissociated LiNO3 with Fast Release Speed for Stable Lithium Metal Batteries with 400 Wh kg(-1) Energy Density.SMALL,9.
MLA	Yang, Huicong,et al."An Interlayer Containing Dissociated LiNO3 with Fast Release Speed for Stable Lithium Metal Batteries with 400 Wh kg(-1) Energy Density".SMALL (2022):9.