Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature | |
Shi, Chunxiang1; Hu, Weijin2; Li, Ji2; Li, Bing2; Ren, Weijun2; Zhang, Zhidong2 | |
Corresponding Author | Hu, Weijin(wjhu@imr.ac.cn) |
2022-08-01 | |
Source Publication | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
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ISSN | 0304-8853 |
Volume | 555Pages:6 |
Abstract | Field-induced magnetic transitions with large magnetization difference and mitigated thermal loss are highly desirable for the development of magnetocaloric materials used for magnetic refrigeration. Here, we report the magnetocaloric effect (MCE) in antiferromagnetic carbide Dy2Cr2C3. Both the inverse MCE (with positive magnetic entropy change delta S-M) and conventional MCE (with negative delta S-M) have been observed, which are attributed to a field-induced first-order metamagnetic transition from antiferromagnetic to ferromagnetic state and a second-order ferromagnetic to paramagnetic transition, respectively. A maximum delta S-M of 13.5 J/kg K at 27 K for a field change of 5 T, and correspondingly a refrigerant cooling power of 315 J/kg in a wide working temperature span of 31 K have been achieved. Such a remarkable magnetocaloric response, together with the minor magnetic hysteresis of less than 0.02 T, indicate that Dy2Cr2C3 carbide could be a promising candidate refrigerant for magnetic refrigeration working at temperatures near the liquid H-2. |
Keyword | Magnetocaloric effect Antiferromagnetic Field-induced magnetic transition Magnetic entropy change Carbide |
Funding Organization | National Natural Science Foundation of China ; Liaoning Shihua University |
DOI | 10.1016/j.jmmm.2022.169339 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[52031014] ; National Natural Science Foundation of China[61974147] ; Liaoning Shihua University[2021XJJL-016] |
WOS Research Area | Materials Science ; Physics |
WOS Subject | Materials Science, Multidisciplinary ; Physics, Condensed Matter |
WOS ID | WOS:000806148100001 |
Publisher | ELSEVIER |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/174318 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Hu, Weijin |
Affiliation | 1.Liaoning Shihua Univ, Coll Sci, Fushun 113001, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Shi, Chunxiang,Hu, Weijin,Li, Ji,et al. Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature[J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,2022,555:6. |
APA | Shi, Chunxiang,Hu, Weijin,Li, Ji,Li, Bing,Ren, Weijun,&Zhang, Zhidong.(2022).Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature.JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,555,6. |
MLA | Shi, Chunxiang,et al."Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature".JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 555(2022):6. |
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