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Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature
Shi, Chunxiang1; Hu, Weijin2; Li, Ji2; Li, Bing2; Ren, Weijun2; Zhang, Zhidong2
Corresponding AuthorHu, Weijin(wjhu@imr.ac.cn)
2022-08-01
Source PublicationJOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
ISSN0304-8853
Volume555Pages:6
AbstractField-induced magnetic transitions with large magnetization difference and mitigated thermal loss are highly desirable for the development of magnetocaloric materials used for magnetic refrigeration. Here, we report the magnetocaloric effect (MCE) in antiferromagnetic carbide Dy2Cr2C3. Both the inverse MCE (with positive magnetic entropy change delta S-M) and conventional MCE (with negative delta S-M) have been observed, which are attributed to a field-induced first-order metamagnetic transition from antiferromagnetic to ferromagnetic state and a second-order ferromagnetic to paramagnetic transition, respectively. A maximum delta S-M of 13.5 J/kg K at 27 K for a field change of 5 T, and correspondingly a refrigerant cooling power of 315 J/kg in a wide working temperature span of 31 K have been achieved. Such a remarkable magnetocaloric response, together with the minor magnetic hysteresis of less than 0.02 T, indicate that Dy2Cr2C3 carbide could be a promising candidate refrigerant for magnetic refrigeration working at temperatures near the liquid H-2.
KeywordMagnetocaloric effect Antiferromagnetic Field-induced magnetic transition Magnetic entropy change Carbide
Funding OrganizationNational Natural Science Foundation of China ; Liaoning Shihua University
DOI10.1016/j.jmmm.2022.169339
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[52031014] ; National Natural Science Foundation of China[61974147] ; Liaoning Shihua University[2021XJJL-016]
WOS Research AreaMaterials Science ; Physics
WOS SubjectMaterials Science, Multidisciplinary ; Physics, Condensed Matter
WOS IDWOS:000806148100001
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/174318
Collection中国科学院金属研究所
Corresponding AuthorHu, Weijin
Affiliation1.Liaoning Shihua Univ, Coll Sci, Fushun 113001, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Shi, Chunxiang,Hu, Weijin,Li, Ji,et al. Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature[J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,2022,555:6.
APA Shi, Chunxiang,Hu, Weijin,Li, Ji,Li, Bing,Ren, Weijun,&Zhang, Zhidong.(2022).Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature.JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,555,6.
MLA Shi, Chunxiang,et al."Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature".JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 555(2022):6.
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