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Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature
Shi, Chunxiang1; Hu, Weijin2; Li, Ji2; Li, Bing2; Ren, Weijun2; Zhang, Zhidong2
通讯作者Hu, Weijin(wjhu@imr.ac.cn)
2022-08-01
发表期刊JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
ISSN0304-8853
卷号555页码:6
摘要Field-induced magnetic transitions with large magnetization difference and mitigated thermal loss are highly desirable for the development of magnetocaloric materials used for magnetic refrigeration. Here, we report the magnetocaloric effect (MCE) in antiferromagnetic carbide Dy2Cr2C3. Both the inverse MCE (with positive magnetic entropy change delta S-M) and conventional MCE (with negative delta S-M) have been observed, which are attributed to a field-induced first-order metamagnetic transition from antiferromagnetic to ferromagnetic state and a second-order ferromagnetic to paramagnetic transition, respectively. A maximum delta S-M of 13.5 J/kg K at 27 K for a field change of 5 T, and correspondingly a refrigerant cooling power of 315 J/kg in a wide working temperature span of 31 K have been achieved. Such a remarkable magnetocaloric response, together with the minor magnetic hysteresis of less than 0.02 T, indicate that Dy2Cr2C3 carbide could be a promising candidate refrigerant for magnetic refrigeration working at temperatures near the liquid H-2.
关键词Magnetocaloric effect Antiferromagnetic Field-induced magnetic transition Magnetic entropy change Carbide
资助者National Natural Science Foundation of China ; Liaoning Shihua University
DOI10.1016/j.jmmm.2022.169339
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[52031014] ; National Natural Science Foundation of China[61974147] ; Liaoning Shihua University[2021XJJL-016]
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Multidisciplinary ; Physics, Condensed Matter
WOS记录号WOS:000806148100001
出版者ELSEVIER
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/174318
专题中国科学院金属研究所
通讯作者Hu, Weijin
作者单位1.Liaoning Shihua Univ, Coll Sci, Fushun 113001, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
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GB/T 7714
Shi, Chunxiang,Hu, Weijin,Li, Ji,et al. Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature[J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,2022,555:6.
APA Shi, Chunxiang,Hu, Weijin,Li, Ji,Li, Bing,Ren, Weijun,&Zhang, Zhidong.(2022).Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature.JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,555,6.
MLA Shi, Chunxiang,et al."Large magnetocaloric effect in antiferromagnetic ternary carbide Dy2Cr2C3 around liquid hydrogen temperature".JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 555(2022):6.
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