An Ion-Sieving Janus Separator toward Planar Electrodeposition for Deeply Rechargeable Zn-Metal Anodes

doi:10.1002/adma.202205175

IMR OpenIR

	An Ion-Sieving Janus Separator toward Planar Electrodeposition for Deeply Rechargeable Zn-Metal Anodes
	Zhang, Xiaotan 1; Li, Jiangxu 2; Qi, Kaiwen 3; Yang, Yongqiang 1; Liu, Dongyan 2; Wang, Tianqi 1; Liang, Shuquan 1; Lu, Bingan 4; Zhu, Yongchun 3; Zhou, Jiang 1
通讯作者	Zhu, Yongchun(ychzhu@ustc.edu.cn) ; Zhou, Jiang(zhou_jiang@csu.edu.cn)
	2022-08-21
发表期刊	ADVANCED MATERIALS
ISSN	0935-9648
页码	9
摘要	The irregular and random electrodeposition of zinc has emerged as a non-negligible barrier for deeply rechargeable aqueous zinc (Zn)-ion batteries (AZIBs), yet traditional texture regulation of the Zn substrate cannot continuously induce uniform Zn deposition. Here, a Janus separator is constructed via parallelly grown graphene sheets modified with sulfonic cellulose on one side of the commercial glass fiber separator through the spin-coating technique. The Janus separator can consistently regulate Zn growth toward a locked crystallographic orientation of Zn(002) texture to intercept dendrites. Furthermore, the separator can spontaneously repel SO42- and anchor H+ while allowing effective transport of Zn2+ to alleviate side reactions. Accordingly, the Zn symmetric cell harvests a long-term lifespan over 1400 h at 10 mA cm(-2)/10 mAh cm(-2) and endures stable cycling over 220 h even at a high depth of discharge (DOD) of 56%. The Zn/carbon nanotube (CNT)-MnO2 cell achieves an outstanding capacity retention of 95% at 1 A g(-1) after 1900 cycles. Furthermore, the Zn/NH4V4O10 pouch cell with a Janus separator delivers an initial capacity of 178 mAh g(-1) and a high capacity retention of 87.4% after 260 cycles. This work provides a continuous regulation approach to achieve crystallographic homogeneity of the Zn anode, which can be suitable for other metal batteries.
关键词	ionic selectivity Janus separators reversibility Zn(002) texture Zn-metal anodes
资助者	National Natural Science Foundation of China ; Hunan Natural Science Fund for Distinguished Young Scholar ; Program of Youth Talent Support for Hunan Province ; Innovation-Driven Project of Central South University
DOI	10.1002/adma.202205175
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51972346] ; National Natural Science Foundation of China[21875238] ; National Natural Science Foundation of China[51932011] ; Hunan Natural Science Fund for Distinguished Young Scholar[2021JJ10064] ; Program of Youth Talent Support for Hunan Province[2020RC3011] ; Innovation-Driven Project of Central South University[2020CX024]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000842298400001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：158[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174471
专题	中国科学院金属研究所
通讯作者	Zhu, Yongchun; Zhou, Jiang
作者单位	1.Cent South Univ, Sch Mat Sci & Engn, Hunan Prov Key Lab Elect Packaging & Adv Funct Ma, Changsha 410083, Hunan, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 3.Univ Sci & Technol China, Dept Appl Chem, Hefei 230026, Anhui, Peoples R China 4.Hunan Univ, Sch Phys & Elect, Changsha 410082, Hunan, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xiaotan,Li, Jiangxu,Qi, Kaiwen,et al. An Ion-Sieving Janus Separator toward Planar Electrodeposition for Deeply Rechargeable Zn-Metal Anodes[J]. ADVANCED MATERIALS,2022:9.
APA	Zhang, Xiaotan.,Li, Jiangxu.,Qi, Kaiwen.,Yang, Yongqiang.,Liu, Dongyan.,...&Zhou, Jiang.(2022).An Ion-Sieving Janus Separator toward Planar Electrodeposition for Deeply Rechargeable Zn-Metal Anodes.ADVANCED MATERIALS,9.
MLA	Zhang, Xiaotan,et al."An Ion-Sieving Janus Separator toward Planar Electrodeposition for Deeply Rechargeable Zn-Metal Anodes".ADVANCED MATERIALS (2022):9.