Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis

doi:10.1039/d2qi00892k

IMR OpenIR

	Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis
	Yu, Zhipeng 1,2,3; Si, Chaowei 4; Javier Escobar-Bedia, Francisco 5; LaGrow, Alec P.1; Xu, Junyuan 6; Sabater, Maria J.5; Amorim, Isilda 1; Araujo, Ana 1,2,3; Sousa, Juliana P. S.1; Meng, Lijian 7; Faria, Joaquim Luis 2,3; Concepcion, Patricia 5; Li, Bo 4; Liu, Lifeng 1
通讯作者	Li, Bo(boli@imr.ac.cn) ; Liu, Lifeng(lifeng.liu@inl.int)
	2022-06-24
发表期刊	INORGANIC CHEMISTRY FRONTIERS
ISSN	2052-1553
页码	9
摘要	Atomically dispersed catalysts (ADCs) have recently drawn considerable interest for use in water electrolysis to produce hydrogen, because they allow for maximal utilization of metal species, particularly the expensive and scarce platinum group metals. Herein, we report the electrocatalytic performance of atomically dispersed ruthenium catalysts (Ru ADCs) with ultralow Ru loading (0.2 wt%). The as-obtained Ru ADCs (Ru (0.2)-NC) are active for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), which only require a low overpotential (eta) of 47.1 and 72.8 mV to deliver 10 mA cm(-2) for HER in 0.5 M H2SO4 and 1.0 M KOH, respectively, and of 300 mV for OER in 1.0 M KOH, showing favorable bifunctionality. Density functional theory (DFT) calculations reveal that the Ru-N bonding plays an important role in lowering the energy barrier of the reactions, boosting the HER and OER activities. Furthermore, the bipolar membrane (BPM) water electrolysis using the bifunctional Ru (0.2)-NC as both HER and OER catalysts can afford 10 mA cm(-2) under a low cell voltage of only 0.89 V, and does not show any performance decay upon 100 h continuous operation, showing great potential for energy-saving hydrogen production.
资助者	National Innovation Agency of Portugal ; Natural Science Foundation of LiaoNing Province, China ; China Scholarship Council ; FCT/MCTES (PIDDAC) ; 2DMAT4FUEL (COMPETE2020 - FCT/MCTES - PIDDAC, Portugal)
DOI	10.1039/d2qi00892k
收录类别	SCI
语种	英语
资助项目	National Innovation Agency of Portugal[POCI-01-0247-FEDER-046109] ; Natural Science Foundation of LiaoNing Province, China[20180510014] ; China Scholarship Council[201806150015] ; FCT/MCTES (PIDDAC)[LA/P/0045/2020] ; FCT/MCTES (PIDDAC)[UIDB/50020/2020] ; FCT/MCTES (PIDDAC)[UIDP/50020/2020] ; 2DMAT4FUEL (COMPETE2020 - FCT/MCTES - PIDDAC, Portugal)[POCI-01-0145-FEDER-029600]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000819504900001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：27[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/174984
专题	中国科学院金属研究所
通讯作者	Li, Bo; Liu, Lifeng
作者单位	1.Int Iberian Nanotechnol Lab INL, Clean Energy Cluster, Ave Mestre Jose Veiga, P-4715330 Braga, Portugal 2.Univ Porto, Fac Engn, LSRE LCM Lab Separat & React Engn, Lab Catalysis & Mat, Rua Dr Roberto Frias, P-4200465 Porto, Portugal 3.Univ Porto, Fac Engn, ALiCE Associate Lab Chem Engn, Rua Dr Roberto Frias, P-4200165 Porto, Portugal 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 5.Univ Politecn Valencia Consejo Super Invest Cient, Inst Tecnol Quim, Ave Naranjos S-N, Valencia 46022, Spain 6.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Adv Spectra Electrochem & Li On Batteries, Dalian 116023, Peoples R China 7.Inst Politecn Porto, Inst Super Engn Porto, Ctr Innovat Engn & Ind Technol, P-4249015 Porto, Portugal
推荐引用方式 GB/T 7714	Yu, Zhipeng,Si, Chaowei,Javier Escobar-Bedia, Francisco,et al. Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis[J]. INORGANIC CHEMISTRY FRONTIERS,2022:9.
APA	Yu, Zhipeng.,Si, Chaowei.,Javier Escobar-Bedia, Francisco.,LaGrow, Alec P..,Xu, Junyuan.,...&Liu, Lifeng.(2022).Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis.INORGANIC CHEMISTRY FRONTIERS,9.
MLA	Yu, Zhipeng,et al."Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis".INORGANIC CHEMISTRY FRONTIERS (2022):9.