| Achieving High-Temperature Multiferroism by Atomic Architecture | |
| Cao, Yi1,3; Tang, Yun-Long1; Zhu, Yin-Lian1,2; Wang, Yujia1; Liu, Nan1,3; Zou, Min-Jie2,4; Liu, Jiaqi1,3; Feng, Yan-Peng2,4; Geng, Wan-Rong2,4; Ma, Xiu-Liang1,2,4 | |
| Corresponding Author | Zhu, Yin-Lian(zhuyinlian@sslab.org.cn) |
| 2023-01-09 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
 |
| ISSN | 1944-8244 |
| Pages | 9 |
| Abstract | Materials with multiple order parameters, typically, in which ferroelec-tricity and magnetism are coupled, are illuminative for next-generation multifunctional electronics. However, searching for such single-phase multiferroics is challenging owing to antagonistic orbital occupancy and chemical bonding requirements for polarity and magnetism. Appropriate multiferroic candidates have been proposed, but their practical implementation is impeded by the low working temperature, weak coupling between ferroic orders, or antiparallel spin alignment in magnetic sublattices. Here, we report a family of single-phase multiferroic materials in which high-temperature magnetism and voltage-switchable ferroelectricity are coupled. Using pulsed laser deposition, we have fabricated single-crystalline thin films incorporating a uniformly percolated open-shell dn framework, which are composed of Fe cations with B-site occupancy and exhibit long-range spin ordering into the displacive ferroelectric PbTiO3 lattice, as demonstrated by atomically resolved chemical analysis. The tetragonal polar Pb(Ti1-x,Fex)O3 (PFT(x), x <= 0.10) family exhibits a switchable ferroelectric nature and magnetic interaction with a moderate coercive field of around 300 Oe at room temperature. Notably, the magnetic order even persists above 500 K, which is higher than already reported potential multiferroic candidates until now. Our strategy of merging a spin-ordered sublattice into inherent ferroelectrics via atomic occupancy engineering provides an available pathway for highly thermally stable multiferroic and spintronic applications. |
| Keyword | high-temperature multiferroics magnetoelectric coupling chemical engineering dilute magnetic oxides atomic occupancy |
| Funding Organization | National Natural Science Foundation of China ; Key Research Program of Frontier Sciences CAS ; Shenyang National Laboratory for Materials Science ; Scientific Instrument Developing Project of CAS ; Youth Innovation Promotion Association CAS ; China National Postdoctoral Program for Innovative Talents |
| DOI | 10.1021/acsami.2c20122 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51971223] ; National Natural Science Foundation of China[51922100] ; National Natural Science Foundation of China[52122101] ; Key Research Program of Frontier Sciences CAS[QYZDJ-SSW-JSC010] ; Shenyang National Laboratory for Materials Science[L2019R06] ; Shenyang National Laboratory for Materials Science[L2019R08] ; Shenyang National Laboratory for Materials Science[L2019F01] ; Shenyang National Laboratory for Materials Science[L2019F13] ; Scientific Instrument Developing Project of CAS[YJKYYQ20200066] ; Youth Innovation Promotion Association CAS[2021187] ; Youth Innovation Promotion Association CAS[Y202048] ; China National Postdoctoral Program for Innovative Talents[BX2021348] |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000914747400001 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/175204 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Zhu, Yin-Lian |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Songshan Lake Mat Lab, Bay Area Ctr Electron Microscopy, Dongguan 523808, Guangdong, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Cao, Yi,Tang, Yun-Long,Zhu, Yin-Lian,et al. Achieving High-Temperature Multiferroism by Atomic Architecture[J]. ACS APPLIED MATERIALS & INTERFACES,2023:9. |
| APA | Cao, Yi.,Tang, Yun-Long.,Zhu, Yin-Lian.,Wang, Yujia.,Liu, Nan.,...&Ma, Xiu-Liang.(2023).Achieving High-Temperature Multiferroism by Atomic Architecture.ACS APPLIED MATERIALS & INTERFACES,9. |
| MLA | Cao, Yi,et al."Achieving High-Temperature Multiferroism by Atomic Architecture".ACS APPLIED MATERIALS & INTERFACES (2023):9. |
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