| Direct transformation of fossil carbon into chemicals: A review | |
| Fan, Jingyuan1; Gao, Kang1; Zhang, Peng1; Dang, Yuying1; Ding, Yuxiao1; Zhang, Bingsen2 | |
| Corresponding Author | Gao, Kang(gaokang@licp.cas.cn) ; Ding, Yuxiao(yuxiaoding@licp.cas.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) |
| 2023-02-01 | |
| Source Publication | JOURNAL OF ENERGY CHEMISTRY
 |
| ISSN | 2095-4956 |
| Volume | 77Pages:247-269 |
| Abstract | Despite the long tradition of fossil carbon (coal, char, and related carbon-based materials) for fueling mankind, the science of transforming them into chemicals is still demandingly progressing in the current energy scenario, especially when considering its responsibilities to the global climate change. Traditionally, there are four routes of preparing chemicals directly from fossil carbon, including hydro-gasification, gasification, direct liquefaction, and oxidation, in the macroscope of gas-solid reaction (hy-drogasification and gasification) and liquid-solid reaction (direct liquefaction and oxidation). When the study goes to microscale, the gas-solid reaction can be considered as the reaction between the severe condensed radicals and gas, while the liquid-solid reaction is the direct reaction between the radical and the activated-molecule. To have a full overview of the area, this review systematically summarizes the main factors in these processes and shows our own perspectives as follows, (i) stabilizing the free rad-icals generated from coal and then directly converting them has the highest efficiency in coal utilization; (ii) the research on the self-catalytic process of coal structure will have a profound impact on the direct preparation of chemicals from fossil carbon. Further discussions are also proposed to guide the future study of the area into a more sustainable direction.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Publishedby ELSEVIER B.V. and Science Press. All rights reserved. |
| Keyword | Fossil carbon Coal-based carbon materials Direct fossil carbon conversion processes Hydrogasification Gasification Direct liquefaction Oxidation |
| Funding Organization | National Natural Science Foundation of China ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy ; Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
| DOI | 10.1016/j.jechem.2022.10.030 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[52161145403] ; National Natural Science Foundation of China[22072164] ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy ; Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences ; [YLU-DNL Fund 2022002] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000917749900001 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/175324 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Gao, Kang; Ding, Yuxiao; Zhang, Bingsen |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Fan, Jingyuan,Gao, Kang,Zhang, Peng,et al. Direct transformation of fossil carbon into chemicals: A review[J]. JOURNAL OF ENERGY CHEMISTRY,2023,77:247-269. |
| APA | Fan, Jingyuan,Gao, Kang,Zhang, Peng,Dang, Yuying,Ding, Yuxiao,&Zhang, Bingsen.(2023).Direct transformation of fossil carbon into chemicals: A review.JOURNAL OF ENERGY CHEMISTRY,77,247-269. |
| MLA | Fan, Jingyuan,et al."Direct transformation of fossil carbon into chemicals: A review".JOURNAL OF ENERGY CHEMISTRY 77(2023):247-269. |
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