Direct transformation of fossil carbon into chemicals: A review

doi:10.1016/j.jechem.2022.10.030

IMR OpenIR

	Direct transformation of fossil carbon into chemicals: A review
	Fan, Jingyuan 1; Gao, Kang 1; Zhang, Peng 1; Dang, Yuying 1; Ding, Yuxiao 1; Zhang, Bingsen 2
通讯作者	Gao, Kang(gaokang@licp.cas.cn) ; Ding, Yuxiao(yuxiaoding@licp.cas.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn)
	2023-02-01
发表期刊	JOURNAL OF ENERGY CHEMISTRY
ISSN	2095-4956
卷号	77 页码:247-269
摘要	Despite the long tradition of fossil carbon (coal, char, and related carbon-based materials) for fueling mankind, the science of transforming them into chemicals is still demandingly progressing in the current energy scenario, especially when considering its responsibilities to the global climate change. Traditionally, there are four routes of preparing chemicals directly from fossil carbon, including hydro-gasification, gasification, direct liquefaction, and oxidation, in the macroscope of gas-solid reaction (hy-drogasification and gasification) and liquid-solid reaction (direct liquefaction and oxidation). When the study goes to microscale, the gas-solid reaction can be considered as the reaction between the severe condensed radicals and gas, while the liquid-solid reaction is the direct reaction between the radical and the activated-molecule. To have a full overview of the area, this review systematically summarizes the main factors in these processes and shows our own perspectives as follows, (i) stabilizing the free rad-icals generated from coal and then directly converting them has the highest efficiency in coal utilization; (ii) the research on the self-catalytic process of coal structure will have a profound impact on the direct preparation of chemicals from fossil carbon. Further discussions are also proposed to guide the future study of the area into a more sustainable direction.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Publishedby ELSEVIER B.V. and Science Press. All rights reserved.
关键词	Fossil carbon Coal-based carbon materials Direct fossil carbon conversion processes Hydrogasification Gasification Direct liquefaction Oxidation
资助者	National Natural Science Foundation of China ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy ; Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences
DOI	10.1016/j.jechem.2022.10.030
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52161145403] ; National Natural Science Foundation of China[22072164] ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy ; Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences ; [YLU-DNL Fund 2022002]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000917749900001
出版者	ELSEVIER
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/175324
专题	中国科学院金属研究所
通讯作者	Gao, Kang; Ding, Yuxiao; Zhang, Bingsen
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Fan, Jingyuan,Gao, Kang,Zhang, Peng,et al. Direct transformation of fossil carbon into chemicals: A review[J]. JOURNAL OF ENERGY CHEMISTRY,2023,77:247-269.
APA	Fan, Jingyuan,Gao, Kang,Zhang, Peng,Dang, Yuying,Ding, Yuxiao,&Zhang, Bingsen.(2023).Direct transformation of fossil carbon into chemicals: A review.JOURNAL OF ENERGY CHEMISTRY,77,247-269.
MLA	Fan, Jingyuan,et al."Direct transformation of fossil carbon into chemicals: A review".JOURNAL OF ENERGY CHEMISTRY 77(2023):247-269.