| The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations | |
| Lu, Xingyu1,2; Qi, Ke1,2; Wang, Di1,2,3; Dai, Xueya1,2; Qi, Wei1,2 | |
| Corresponding Author | Qi, Wei(wqi@imr.ac.cn) |
| 2022-09-23 | |
| Source Publication | CATALYSIS SCIENCE & TECHNOLOGY
 |
| ISSN | 2044-4753 |
| Pages | 7 |
| Abstract | 2,5-Furandicarboxylic acid (FDCA) is a high-value platform molecule that can replace the fossil derivative terephthalic acid in the synthesis of important chemicals. FDCA can be synthesized from the oxidation of the biomass derivative 5-hydroxymethylfurfural (HMF). In this study, we loaded Cu-based catalysts with different morphologies and chemical states on carbon paper, and it was found that the Cu nanocrystalline/carbon paper catalyst with a thin and scattered dendrite structure (Cu(NSD)/CP) exhibits the best performance for the electrooxidation of HMF (96% yield and 100% selectivity for FDCA), which is attributed to the fact that the Cu-0 and Cu1+ species in the catalyst are easily oxidized in situ to Cu2+ species, showing high catalytic activity during the reaction process. This paper highlights the importance of the identification of active sites and the rational design of catalysts based on structure-function relations. |
| Funding Organization | NSFC of China ; Natural Science Foundation of Liaoning Province of China ; China Baowu Low Carbon Metallurgy Innovation |
| DOI | 10.1039/d2cy01165d |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | NSFC of China[22072163] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; China Baowu Low Carbon Metallurgy Innovation[Foudation-BWLCF202113] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000865265600001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/176017 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Qi, Wei |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 3.Shenyang Pharmaceut Univ, Sch Pharm, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Lu, Xingyu,Qi, Ke,Wang, Di,et al. The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations[J]. CATALYSIS SCIENCE & TECHNOLOGY,2022:7. |
| APA | Lu, Xingyu,Qi, Ke,Wang, Di,Dai, Xueya,&Qi, Wei.(2022).The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations.CATALYSIS SCIENCE & TECHNOLOGY,7. |
| MLA | Lu, Xingyu,et al."The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations".CATALYSIS SCIENCE & TECHNOLOGY (2022):7. |
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