MOF-derived W/Zr bimetallic oxides@Carbon for comprehensively remedying melamine foam electrode defects in vanadium redox flow batteries

doi:10.1016/j.cej.2023.143360

IMR OpenIR

	MOF-derived W/Zr bimetallic oxides@Carbon for comprehensively remedying melamine foam electrode defects in vanadium redox flow batteries
	Zhang, Xihao 1,2; Zhang, Denghua 1,2; Liu, Lansong 1,2; Zhang, Kaiyue 3; Zhang, Yifan 1,2; Zhao, Jinling 1; Han, Linting 4; Jing, Minghua 5; Liu, Jianguo 1; Yan, Chuanwei 1
通讯作者	Jing, Minghua(mhjing@lnu.edu.cn) ; Liu, Jianguo(jgliu@imr.ac.cn)
	2023-07-01
发表期刊	CHEMICAL ENGINEERING JOURNAL
ISSN	1385-8947
卷号	467 页码:10
摘要	Due to a series of defects such as low conductivity, poor catalytic activity and unfavorable long-term cycling stability, the comprehensive modification and usage improvement of carbonized melamine foam remain a significant challenge. Here, introducing W site into Zr-UiO-66 framework is proposed to construct W/Zr bimetallic oxides@carbon melamine foam electrode, which exhibits larger specific surface area, higher conductivity and catalytic activity than the pristine MF electrode. Benefiting from the ordered arrangement of W, Zr sites in the MOF precursor, the catalyst has an extremely catalytic activity and ultra-high binding performance of W/Zr bimetallic oxide particles with MF substrate. The electrode W/ZrBO@C-1000 possesses improved specific surface areas, hydrophilicity, higher electrochemical reactivity and reversibility compared to the pristine CMF-1000 electrode, as confirmed by material and electrochemical characterizations. The corresponding VRFB is able to achieved an energy efficiency of 82.43% at 200 mA cm-2, and displays a desirable long-term stability over 500 consecutive charge-discharge cycles. Density function theory further clarifies the underlying catalysis mechanism of bimetallic oxides for vanadium redox reactions. The strategy of introducing bimetallic oxides basing on MOF precursors improves the performance of melamine foam electrodes, which is expected to be a solution to remedy defects and broaden its usage range in other flow batteries.
关键词	Melamine foam Zr-UiO-66 Bimetallic oxides Vanadium redox flow battery Electrode
资助者	National Key R & D Program of China ; National Natural Science Foundation of China ; Central Guidance on Local Science and Technology Development Fund of Liaoning Province ; Department of Science and Technology of Liaoning Province ; Scientific Research Fund Project of the Educational Department of Liaoning Province of China
DOI	10.1016/j.cej.2023.143360
收录类别	SCI
语种	英语
资助项目	National Key R & D Program of China[2022YFB2404901] ; National Natural Science Foundation of China[21975267] ; Central Guidance on Local Science and Technology Development Fund of Liaoning Province[2022JH6/100100001] ; Department of Science and Technology of Liaoning Province[2020 -BS -079] ; Scientific Research Fund Project of the Educational Department of Liaoning Province of China[LJKMZ20220445]
WOS研究方向	Engineering
WOS类目	Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:001001852600001
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/178115
专题	中国科学院金属研究所
通讯作者	Jing, Minghua; Liu, Jianguo
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 3.Shenyang Ligong Univ, Sch Mat Sci & Engn, Shenyang 110159, Liaoning, Peoples R China 4.North Univ China, Sch Chem & Chem Engn, Taiyuan 030051, Shanxi, Peoples R China 5.Liaoning Univ, Inst Rare & Scattered Elements, Coll Chem, Shenyang 110136, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xihao,Zhang, Denghua,Liu, Lansong,et al. MOF-derived W/Zr bimetallic oxides@Carbon for comprehensively remedying melamine foam electrode defects in vanadium redox flow batteries[J]. CHEMICAL ENGINEERING JOURNAL,2023,467:10.
APA	Zhang, Xihao.,Zhang, Denghua.,Liu, Lansong.,Zhang, Kaiyue.,Zhang, Yifan.,...&Yan, Chuanwei.(2023).MOF-derived W/Zr bimetallic oxides@Carbon for comprehensively remedying melamine foam electrode defects in vanadium redox flow batteries.CHEMICAL ENGINEERING JOURNAL,467,10.
MLA	Zhang, Xihao,et al."MOF-derived W/Zr bimetallic oxides@Carbon for comprehensively remedying melamine foam electrode defects in vanadium redox flow batteries".CHEMICAL ENGINEERING JOURNAL 467(2023):10.