| Construction of Co-4 Atomic Clusters to Enable Fe-N-4 Motifs with Highly Active and Durable Oxygen Reduction Performance | |
| Han, Ali1,2; Sun, Wenming3; Wan, Xin4; Cai, Dandan5; Wang, Xijun6; Li, Feng7; Shui, Jianglan4; Wang, Dingsheng2 | |
| Corresponding Author | Wang, Dingsheng(wangdingsheng@mail.tsinghua.edu.cn) |
| 2023-06-14 | |
| Source Publication | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| Pages | 11 |
| Abstract | Fe-N-C catalysts with single-atom Fe-N-4 configurations are highly needed owing to the high activity for oxygen reduction reaction (ORR). However, the limited intrinsic activity and dissatisfactory durability have significantly restrained the practical application of proton-exchange membrane fuel cells (PEMFCs). Here, we demonstrate that constructing adjacent metal atomic clusters (ACs) is effective in boosting the ORR performance and stability of Fe-N-4 catalysts. The integration of Fe-N-4 configurations with highly uniform Co-4 ACs on the N-doped carbon substrate (Co-4@/Fe-1@NC) is realized through a "pre-constrained" strategy using Co-4 molecular clusters and Fe(acac)(3) implanted carbon precursors. The as-developed Co-4@/Fe-1@NC catalyst exhibits excellent ORR activity with a half-wave potential (E-1/2) of 0.835 V vs. RHE in acidic media and a high peak power density of 840 mW cm(-2) in a H-2-O-2 fuel cell test. First-principles calculations further clarify the ORR catalytic mechanism on the identified Fe-N-4 that modified with Co-4 ACs. This work provides a viable strategy for precisely establishing atomically dispersed polymetallic centers catalysts for efficient energy-related catalysis. |
| Keyword | Atomic Clusters Fuel Cell Oxygen Reduction Reaction Single-Atom Catalysts |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province-Outstanding Youth Foundation |
| DOI | 10.1002/anie.202303185 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2018YFA0702003] ; National Key R&D Program of China[2021YFA1501500] ; National Natural Science Foundation of China[22202214] ; National Natural Science Foundation of China[21890383] ; National Natural Science Foundation of China[22171157] ; National Natural Science Foundation of China[21875097] ; National Natural Science Foundation of China[22068008] ; Natural Science Foundation of Liaoning Province-Outstanding Youth Foundation[2022-YQ-02] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:001006359000001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/178265 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Wang, Dingsheng |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 3.Capital Normal Univ, Dept Chem, Beijing Key Lab Opt Mat & Photon Devices, Beijing 100048, Peoples R China 4.Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China 5.Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuhai 519082, Peoples R China 6.Northwestern Univ, Dept Chem & Biol Engn, 2145 Sheridan Rd, Evanston, IL 60208 USA 7.Fudan Univ, Lab Adv Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, 220 Handan, Shanghai 200433, Peoples R China |
| Recommended Citation GB/T 7714 | Han, Ali,Sun, Wenming,Wan, Xin,et al. Construction of Co-4 Atomic Clusters to Enable Fe-N-4 Motifs with Highly Active and Durable Oxygen Reduction Performance[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2023:11. |
| APA | Han, Ali.,Sun, Wenming.,Wan, Xin.,Cai, Dandan.,Wang, Xijun.,...&Wang, Dingsheng.(2023).Construction of Co-4 Atomic Clusters to Enable Fe-N-4 Motifs with Highly Active and Durable Oxygen Reduction Performance.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,11. |
| MLA | Han, Ali,et al."Construction of Co-4 Atomic Clusters to Enable Fe-N-4 Motifs with Highly Active and Durable Oxygen Reduction Performance".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023):11. |
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