Study on volatilization behaviour of BOF converter slag containing CaCl2 | |
Yan, Ziwen1,2,3,4; Deng, Zhiyin1,2,5,6; Zhu, Miaoyong1,2,7,8 | |
Corresponding Author | Deng, Zhiyin(dengzy@smm.neu.edu.cn) ; Zhu, Miaoyong(myzhu@mail.neu.edu.cn) |
2023-08-09 | |
Source Publication | IRONMAKING & STEELMAKING
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ISSN | 0301-9233 |
Volume | 50Issue:7Pages:900-907 |
Abstract | The volatilization behaviour of CaCl2-containing basic oxygen furnace (BOF) slags was investigated in laboratory at steelmaking temperature. During the melting process, the volatilization ratio was measured, and the volatile compounds were collected with some conductive tapes. Thermogravimetric analysis was conducted to clarify the volatilization of CaCl2-containing slags, and the volatilization ratio was also calculated by the thermodynamic software HSC. It was found that volatilization takes place in both CaCl2-containing and CaF2-containing BOF slags, but their influential mechanisms are different. FeCl2 is the main volatile compound in CaCl2-containing BOF slags. The increasing contents of CaCl2 and FeO in these slags are favourable for volatilization, while higher slag basicity plays the opposite role. In the case of CaF2-containing BOF slags, the volatilization compounds have little relation to the FeO content in the slags, and the volatilization ratio is smaller than that of CaCl2-containing BOF slag. |
Keyword | BOF steelmaking slag CaCl2 CaF2 FeCl2 FeO volatile compound volatilization behaviour melting process |
Funding Organization | National Natural Science Foundation of China |
DOI | 10.1080/03019233.2023.2221940 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[U20A20272] ; National Natural Science Foundation of China[52074073] |
WOS Research Area | Metallurgy & Metallurgical Engineering |
WOS Subject | Metallurgy & Metallurgical Engineering |
WOS ID | WOS:001011182200001 |
Publisher | TAYLOR & FRANCIS LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/178583 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Deng, Zhiyin; Zhu, Miaoyong |
Affiliation | 1.Northeastern Univ, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang, Peoples R China 2.Northeastern Univ, Sch Met, Shenyang, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China 4.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Peoples R China 5.Northeastern Univ, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China 6.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China 7.Northeastern Univ, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China 8.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China |
Recommended Citation GB/T 7714 | Yan, Ziwen,Deng, Zhiyin,Zhu, Miaoyong. Study on volatilization behaviour of BOF converter slag containing CaCl2[J]. IRONMAKING & STEELMAKING,2023,50(7):900-907. |
APA | Yan, Ziwen,Deng, Zhiyin,&Zhu, Miaoyong.(2023).Study on volatilization behaviour of BOF converter slag containing CaCl2.IRONMAKING & STEELMAKING,50(7),900-907. |
MLA | Yan, Ziwen,et al."Study on volatilization behaviour of BOF converter slag containing CaCl2".IRONMAKING & STEELMAKING 50.7(2023):900-907. |
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