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Study on volatilization behaviour of BOF converter slag containing CaCl2
Yan, Ziwen1,2,3,4; Deng, Zhiyin1,2,5,6; Zhu, Miaoyong1,2,7,8
通讯作者Deng, Zhiyin(dengzy@smm.neu.edu.cn) ; Zhu, Miaoyong(myzhu@mail.neu.edu.cn)
2023-08-09
发表期刊IRONMAKING & STEELMAKING
ISSN0301-9233
卷号50期号:7页码:900-907
摘要The volatilization behaviour of CaCl2-containing basic oxygen furnace (BOF) slags was investigated in laboratory at steelmaking temperature. During the melting process, the volatilization ratio was measured, and the volatile compounds were collected with some conductive tapes. Thermogravimetric analysis was conducted to clarify the volatilization of CaCl2-containing slags, and the volatilization ratio was also calculated by the thermodynamic software HSC. It was found that volatilization takes place in both CaCl2-containing and CaF2-containing BOF slags, but their influential mechanisms are different. FeCl2 is the main volatile compound in CaCl2-containing BOF slags. The increasing contents of CaCl2 and FeO in these slags are favourable for volatilization, while higher slag basicity plays the opposite role. In the case of CaF2-containing BOF slags, the volatilization compounds have little relation to the FeO content in the slags, and the volatilization ratio is smaller than that of CaCl2-containing BOF slag.
关键词BOF steelmaking slag CaCl2 CaF2 FeCl2 FeO volatile compound volatilization behaviour melting process
资助者National Natural Science Foundation of China
DOI10.1080/03019233.2023.2221940
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[U20A20272] ; National Natural Science Foundation of China[52074073]
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:001011182200001
出版者TAYLOR & FRANCIS LTD
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/178583
专题中国科学院金属研究所
通讯作者Deng, Zhiyin; Zhu, Miaoyong
作者单位1.Northeastern Univ, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang, Peoples R China
2.Northeastern Univ, Sch Met, Shenyang, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China
4.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Peoples R China
5.Northeastern Univ, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China
6.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
7.Northeastern Univ, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China
8.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
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Yan, Ziwen,Deng, Zhiyin,Zhu, Miaoyong. Study on volatilization behaviour of BOF converter slag containing CaCl2[J]. IRONMAKING & STEELMAKING,2023,50(7):900-907.
APA Yan, Ziwen,Deng, Zhiyin,&Zhu, Miaoyong.(2023).Study on volatilization behaviour of BOF converter slag containing CaCl2.IRONMAKING & STEELMAKING,50(7),900-907.
MLA Yan, Ziwen,et al."Study on volatilization behaviour of BOF converter slag containing CaCl2".IRONMAKING & STEELMAKING 50.7(2023):900-907.
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