Mesoporous Single Crystal NiS2 Microparticles with FeS Clusters Decorated on the Pore Walls for Efficient Electrocatalytic Oxygen Evolution

doi:10.1002/adfm.202307947

IMR OpenIR

	Mesoporous Single Crystal NiS2 Microparticles with FeS Clusters Decorated on the Pore Walls for Efficient Electrocatalytic Oxygen Evolution
	Zhang, Lulu 1,2; Rong, Ju 3; Lin, Yunxiang 4,5; Yang, Yongqiang 1; Zhu, Huaze 1,2; Yu, Xiaohua 3; Kang, Xiangdong 1; Chen, Chunlin 1; Cheng, Hui-Ming 1,6; Liu, Gang 1,2
通讯作者	Yang, Yongqiang(yqyang@imr.ac.cn) ; Liu, Gang(gangliu@imr.ac.cn)
	2023-09-08
发表期刊	ADVANCED FUNCTIONAL MATERIALS
ISSN	1616-301X
页码	11
摘要	Abundant active sites and their easy accessibility in a stable and conductive structure are of great importance for efficient electrocatalysts. In principle, activated mesoporous single-crystal microparticles can meet these desired requirements. Here, the Fe-doped NiS2 mesoporous single crystal microparticles decorated with FeS clusters on the pore walls (FeS@MSC-NiS2:Fe) are constructed via a pre-decorated and sequentially seeded mesoporous silica template. Throughout the external and internal surfaces, the Fe-doped NiS2 modulated by the adjacent FeS clusters induces favorable charge distributions and promotes the crucial formation of the active Fe/Ni (oxy)hydroxide. Combined with the spatial enrichment effect of the intermediates in the holey space and the boosted charge transfer within the continuous single-crystalline framework, the dually regulated FeS@MSC-NiS2:Fe as ideal integral microreactors show efficient performances in oxygen evolution reaction. In electrochemical tests, the particulate FeS@MSC-NiS2:Fe requires an overpotential of only 236 mV to reach a current density of 10 mA cm-2 and displays fast reaction kinetics with a Tafel slope of 32.4 mV dec(-1). This study provides an important strategy to construct electrocatalysts with highly active sites and good accessibility.
关键词	electrocatalysts integral microreactors internal decorations mesoporous single crystals oxygen evolution reaction
资助者	National Key R & D Program of China ; National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; directional institutionalized scientific research platform relies on Beijing Synchrotron Radiation Facility of Chinese Academy of Sciences ; New Cornerstone Science Foundation through the XPLORER PRIZE
DOI	10.1002/adfm.202307947
收录类别	SCI
语种	英语
资助项目	National Key R & D Program of China[2021YFA1500800] ; National Natural Science Foundation of China[52072379] ; National Natural Science Foundation of China[51825204] ; National Natural Science Foundation of China[U2202252] ; International Partnership Program of Chinese Academy of Sciences[174321KYSB20200005] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2022190] ; directional institutionalized scientific research platform relies on Beijing Synchrotron Radiation Facility of Chinese Academy of Sciences ; New Cornerstone Science Foundation through the XPLORER PRIZE
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:001064026600001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/179156
专题	中国科学院金属研究所
通讯作者	Yang, Yongqiang; Liu, Gang
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Kunming 650093, Peoples R China 4.Anhui Univ, Inst Phys Sci, Hefei 230601, Peoples R China 5.Anhui Univ, Inst Informat Technol, Hefei 230601, Peoples R China 6.Chinese Acad Sci, Shenzhen Inst Adv Technol, Inst Technol Carbon Neutral, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Lulu,Rong, Ju,Lin, Yunxiang,et al. Mesoporous Single Crystal NiS2 Microparticles with FeS Clusters Decorated on the Pore Walls for Efficient Electrocatalytic Oxygen Evolution[J]. ADVANCED FUNCTIONAL MATERIALS,2023:11.
APA	Zhang, Lulu.,Rong, Ju.,Lin, Yunxiang.,Yang, Yongqiang.,Zhu, Huaze.,...&Liu, Gang.(2023).Mesoporous Single Crystal NiS2 Microparticles with FeS Clusters Decorated on the Pore Walls for Efficient Electrocatalytic Oxygen Evolution.ADVANCED FUNCTIONAL MATERIALS,11.
MLA	Zhang, Lulu,et al."Mesoporous Single Crystal NiS2 Microparticles with FeS Clusters Decorated on the Pore Walls for Efficient Electrocatalytic Oxygen Evolution".ADVANCED FUNCTIONAL MATERIALS (2023):11.