Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials

doi:10.1016/j.pmatsci.2024.101247

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	Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials
	Wang, Zhenxing 1,2,4; Li, Linqing 1; Sun, Zhenhua 2,3; Tang, Pei 2,3; Hu, Guangjian 2; Tan, Jun 1,4; Li, Feng 2,3
通讯作者	Tan, Jun(tanjun@jihualab.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2024-06-01
发表期刊	PROGRESS IN MATERIALS SCIENCE
ISSN	0079-6425
卷号	143 页码:52
摘要	A comprehensive understanding of the relationship between the structure (electron/bulk/surface structures) and redox chemistry in the cathodes was discussed in this Review. First, the attention is given to the comparison of different layered Li-Co-Ni-Mn oxide cathodes, especially the bulk atomic configuration (Section 2.1). Second, corresponding to the distinct layered structure, the electronic structures, Fermi level energies of different redox couples are introduced (Section 2.2). The structural failures induced by the redox chemistry at the deep lithiation state, including bulk phase transition, surface structure degradation, as well as the resulting cracking, cation mixing, oxygen release, dissolution of metal cations, voltage fading and low initial Coulombic efficiency, are discussed (Section 3.1-3.3). Correspondingly, the strategies for stabilizing the structural stability by regulating the redox activity, including bulk atomic doping design, surface engineering, cations mixing, particle morphology, oxygen vacancy and oxygen stacking type, are summarized (Section 4.1-4.3). The advanced characterization techniques, such as X-ray, electron, neutron and nuclear magnetic resonance techniques, are summarized for detecting the cationic/anionic charge state (Section 5.1-5.4). In the last section (Section 6), the promising strategies and future perspectives are highlighted to propel significant breakthroughs in developing high-energy-density LIBs.
关键词	Layered transition oxide cathode materials Structural stability Phase transition Bulk element doping Surface engineering
资助者	National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Foshan Postdoctoral Science Foundation ; Key R & D Plan of Jihua Laboratory ; National Key R & D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Liaoning Revitalization Talents Program
DOI	10.1016/j.pmatsci.2024.101247
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[22209055] ; National Natural Science Foundation of China[22379151] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; China Postdoctoral Science Foundation[2022M721330] ; Foshan Postdoctoral Science Foundation[X221081MS210] ; Key R & D Plan of Jihua Laboratory[X200191TL200] ; National Key R & D Program of China[2022YFB3803400] ; National Key R & D Program of China[2021YFB3800300] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; Liaoning Revitalization Talents Program[XLYC2007080]
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:001186219100001
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/185073
专题	中国科学院金属研究所
通讯作者	Tan, Jun; Li, Feng
作者单位	1.Ji Hua Lab, Foshan 528000, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Foshan Univ, Foshan 528000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Zhenxing,Li, Linqing,Sun, Zhenhua,et al. Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials[J]. PROGRESS IN MATERIALS SCIENCE,2024,143:52.
APA	Wang, Zhenxing.,Li, Linqing.,Sun, Zhenhua.,Tang, Pei.,Hu, Guangjian.,...&Li, Feng.(2024).Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials.PROGRESS IN MATERIALS SCIENCE,143,52.
MLA	Wang, Zhenxing,et al."Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials".PROGRESS IN MATERIALS SCIENCE 143(2024):52.