Optical and magnetic properties of transition-metal ions in tetrahedral and octahedral compounds

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	Optical and magnetic properties of transition-metal ions in tetrahedral and octahedral compounds
	H. F. Li; H. Q. Wang; X. Y. Kuang
	2011
发表期刊	Science China-Physics Mechanics & Astronomy
ISSN	1674-7348
卷号	54 期号:10 页码:1796-1800
摘要	This paper presents the complete energy matrix of the 3d(2) system containing the electron-electron interaction, the ligand-field interaction, the spin-orbit coupling interaction, and the Zeeman interaction, in which the optical spectra and g-factor of V(3+) and Ti(2+) ions in the series of tetrahedral A(II)B(VI) (A(II)=Zn, Cd, B(VI)=S, Se, Te) semiconductor materials are determined. In the investigation of the optical and magnetic properties of these transition-metal ions in the tetrahedral coordination complexes, we compared the data obtained from the transition-metal ions in the tetrahedral coordination complexes with those obtained from the corresponding ions in the octahedral ones, and found that the tetrahedral complexes have weaker crystal-field strength, inverse energy level ordering and stronger covalence effect.
部门归属	[li huifang; wang huaiqian] huaqiao univ, coll engn, quanzhou 362021, peoples r china. [li huifang; kuang xiaoyu] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang xiaoyu] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;wang, hq (reprint author), huaqiao univ, coll engn, quanzhou 362021, peoples r china;scu_whq@163.com
关键词	Epr And Optical Spectra Complete Energy Matrix Ligand-field Theory Tetrahedral Coordination Complexes Octahedral Complexes Transition-metal Ions Electron-paramagnetic-resonance Trigonal Ligand-field Structure Distortion Vanadium Centers Local-structure Znte Crystals Mn2++ Ions Spectra Absorption Epr
URL	查看原文
WOS记录号	WOS:000295213100012
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/30461
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. F. Li,H. Q. Wang,X. Y. Kuang. Optical and magnetic properties of transition-metal ions in tetrahedral and octahedral compounds[J]. Science China-Physics Mechanics & Astronomy,2011,54(10):1796-1800.
APA	H. F. Li,H. Q. Wang,&X. Y. Kuang.(2011).Optical and magnetic properties of transition-metal ions in tetrahedral and octahedral compounds.Science China-Physics Mechanics & Astronomy,54(10),1796-1800.
MLA	H. F. Li,et al."Optical and magnetic properties of transition-metal ions in tetrahedral and octahedral compounds".Science China-Physics Mechanics & Astronomy 54.10(2011):1796-1800.