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Battery Performance and Photocatalytic Activity of Mesoporous Anatase TiO(2) Nanospheres/Graphene Composites by Template-Free Self-Assembly
N. Li; G. Liu; C. Zhen; F. Li; L. L. Zhang; H. M. Cheng
2011
发表期刊Advanced Functional Materials
ISSN1616-301X
卷号21期号:9页码:1717-1722
摘要Nanosized mesoporous anatase TiO(2) particles have important applications in high-performance lithium ion batteries and effi cient photocatalysis. In contrast to the conventional synthesis routes where various soft or hard templates are usually employed, the direct growth of uniform mesoporous anatase TiO(2) nanospheres on graphene sheets by a template-free selfassembly process is presented. Compared to the conventional mesoporous anatase particles consisting of polycrystalline TiO(2), the microstructure of obtained mesoporous anatase nanospheres on graphene sheets is singlecrystal- like. The growth mechanism, lithium ion battery performance, and photocatalytic activity of the resultant mesoporous anatase TiO(2) nanospheres/ graphene composites are thoroughly investigated. In comparison to the reference TiO(2), the composite shows substantial improvement in lithium specifi c capacity from 1 C to 50 C, and photocatalytic removing organic pollutant and hydrogen evolution. More strikingly, the specifi c capacity of the composite at the rate of 50 C is as high as 97 mA h g(-1), 6 times higher than that of the reference TiO(2).
部门归属[li, na; liu, gang; zhen, chao; li, feng; zhang, lili; cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;li, n (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china;fli@imr.ac.cn cheng@imr.ac.cn
关键词Lithium Ion Batteries Reversible Capacity Nanostructured Tio2 Graphene Films Insertion Titania Storage Nanoparticles Sheets
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/30475
专题中国科学院金属研究所
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GB/T 7714
N. Li,G. Liu,C. Zhen,et al. Battery Performance and Photocatalytic Activity of Mesoporous Anatase TiO(2) Nanospheres/Graphene Composites by Template-Free Self-Assembly[J]. Advanced Functional Materials,2011,21(9):1717-1722.
APA N. Li,G. Liu,C. Zhen,F. Li,L. L. Zhang,&H. M. Cheng.(2011).Battery Performance and Photocatalytic Activity of Mesoporous Anatase TiO(2) Nanospheres/Graphene Composites by Template-Free Self-Assembly.Advanced Functional Materials,21(9),1717-1722.
MLA N. Li,et al."Battery Performance and Photocatalytic Activity of Mesoporous Anatase TiO(2) Nanospheres/Graphene Composites by Template-Free Self-Assembly".Advanced Functional Materials 21.9(2011):1717-1722.
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