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Corrosion behavior of Ti(3)AlC(2) in NaOH and H(2)SO(4)
D. Li; Y. Liang; X. X. Liu; Y. C. Zhou
2010
发表期刊Journal of the European Ceramic Society
ISSN0955-2219
卷号30期号:15页码:3227-3234
摘要Passivation behavior, corrosion kinetics and film formation mechanism of Ti(3)AlC(2) in 1 M NaOH and 1 M H(2)SO(4) solutions were investigated by linear potential scan, electrochemical impedance spectroscopy, cyclic voltammetry, SEM and XPS. The corrosion resistance mainly depended on the formation of passivating films on Ti(3)AlC(2) in 1 M NaOH and 1 M H(2)SO(4), which led to different corrosion processes. Ti(3)AlC(2) displayed good corrosion resistance in NaOH due to the formation of dense and protective Ti oxides as the passivating film. However, it exhibited poor corrosion resistance in H(2)SO(4) which attributed to the formation of permeable Ti sub-oxides as the pseudo-passivating film. (C) 2010 Elsevier Ltd. All rights reserved.
部门归属[zhou, yanchun] chinese acad sci, shenyang natl lab mat sci, high performance ceram div, inst met res, shenyang 110016, peoples r china. [li, dan; liang, ying; liu, xiaoxia] northeastern univ, dept chem, shenyang 110819, peoples r china.;zhou, yc (reprint author), chinese acad sci, shenyang natl lab mat sci, high performance ceram div, inst met res, 72 wenhua rd, shenyang 110016, peoples r china;yczhou@imr.ac.cn
关键词Ti(3)Alc(2) Corrosion Electrochemical Measurements Xps Electrochemical-behavior Passive Film Ti3sic2 Ti4aln3 Phases Ti2aln Alloy Hcl Ti
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31205
专题中国科学院金属研究所
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GB/T 7714
D. Li,Y. Liang,X. X. Liu,et al. Corrosion behavior of Ti(3)AlC(2) in NaOH and H(2)SO(4)[J]. Journal of the European Ceramic Society,2010,30(15):3227-3234.
APA D. Li,Y. Liang,X. X. Liu,&Y. C. Zhou.(2010).Corrosion behavior of Ti(3)AlC(2) in NaOH and H(2)SO(4).Journal of the European Ceramic Society,30(15),3227-3234.
MLA D. Li,et al."Corrosion behavior of Ti(3)AlC(2) in NaOH and H(2)SO(4)".Journal of the European Ceramic Society 30.15(2010):3227-3234.
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