The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry

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	The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry
	S. V. Meschel; P. Nash; X. Q. Chen
	2010
发表期刊	Journal of Alloys and Compounds
ISSN	0925-8388
卷号	492 期号:1-2 页码:105-115
摘要	The standard enthalpies of formation of intermetallic compounds of some late 4d and 5d transition metals have been measured by high temperature, direct synthesis calorimetry at 1373 +/- 2 K. The following results in kJ/mol of atoms are reported: NbMn(2) (-10.4 +/- 2.7); NbRu (-0.7 +/- 2.8); RhMo (-4.8 +/- 1.8): PdMn (-45.2 +/- 2.2); Pd(2)Mo (-9.2 +/- 1.9); TaMn(2) (-14.5 +/- 2.5); IrMn(3) (-13.2 +/- 2.8): Pt(3)Cr (-8.8 +/- 3.1); PtMn (-53.6 +/- 1.5); PtMo (-17.9 +/- 2.2); Pt(3)Ta (-21.1 +/- 2.4); and YMn(2) (-2.8 +/- 2.8). The values are compared with predicted values of Miedema and co-workers and with new results from ab initio calculations when available. We will present a systematic picture of how the enthalpies of formation may be related to the atomic number of the transition metal. We will also compare the thermochemical behavior of the Fe, Co, Ni group with the late transition metal alloys. (C) 2009 Elsevier B.V. All rights reserved.
部门归属	[meschel, s. v.; nash, p.] iit, thermal proc technol ctr, chicago, il 60616 usa. [meschel, s. v.] univ chicago, james franck inst, chicago, il 60637 usa. [chen, xing-qiu] chinese acad sci, inst met res, shenyang 110006, peoples r china.;meschel, sv (reprint author), iit, thermal proc technol ctr, 10 w 32nd st, chicago, il 60616 usa;meschel@jfi.uchicago.edu
关键词	Transition Metal Alloys Thermodynamics Enthalpies Total-energy Calculations Wave Basis-set Ab-initio Thermodynamic Properties Intermediate Phases Systems Feti Laves Phases Nb-rh Alloys Cobalt
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WOS记录号	WOS:000276018900043
引用统计	被引频次：31[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31383
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	S. V. Meschel,P. Nash,X. Q. Chen. The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry[J]. Journal of Alloys and Compounds,2010,492(1-2):105-115.
APA	S. V. Meschel,P. Nash,&X. Q. Chen.(2010).The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry.Journal of Alloys and Compounds,492(1-2),105-115.
MLA	S. V. Meschel,et al."The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry".Journal of Alloys and Compounds 492.1-2(2010):105-115.