Observations of anomalies in the anodic behaviour of microcrystalline aluminium | |
B. Zhang; Y. Li; F. H. Wang | |
2010 | |
发表期刊 | Corrosion Science
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ISSN | 0010-938X |
卷号 | 52期号:8页码:2612-2615 |
摘要 | The anodic behaviour of sputtered microcrystalline Al (mc-Al) was investigated in neutral Na(2)SO(4) electrolyte under varied conditions. Our results revealed that Cl(-) addition led to a reduction in the anodic current density, which we considered unusual. Mott-Schottky analysis showed that Cl introduction altered the semiconducting property of the passive film from n-type to p-type, implying that the p-type film can possessed a relative higher stability. Immersion of mc-Al in other electrolytes yielded films with n-type, p-type and positive p-n junction structure. The results also indicate that the p-type film was most stable and the positive p-n junction film least stable. (C) 2010 Elsevier Ltd. All rights reserved. |
部门归属 | [zhang, bo; li, ying; wang, fuhui] chinese acad sci, state key lab corros & protect, inst met res, shenyang 110016, peoples r china.;li, y (reprint author), chinese acad sci, state key lab corros & protect, inst met res, wencui rd 62, shenyang 110016, peoples r china;liying@imr.ac.cn |
关键词 | Aluminium Sputtered Films Passive Films Passive Films Oxide-films Pit Nucleation Chloride-ion Corrosion Iron Impedance Breakdown Alloys Xps |
URL | 查看原文 |
WOS记录号 | WOS:000279094800010 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/31678 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | B. Zhang,Y. Li,F. H. Wang. Observations of anomalies in the anodic behaviour of microcrystalline aluminium[J]. Corrosion Science,2010,52(8):2612-2615. |
APA | B. Zhang,Y. Li,&F. H. Wang.(2010).Observations of anomalies in the anodic behaviour of microcrystalline aluminium.Corrosion Science,52(8),2612-2615. |
MLA | B. Zhang,et al."Observations of anomalies in the anodic behaviour of microcrystalline aluminium".Corrosion Science 52.8(2010):2612-2615. |
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