Fabrication and evaluation of a Ni/La(0.75)Sr(0.25)Cr(0.5)Fe(0.5)O(3-delta) co-impregnated yttria-stabilized zirconia anode for single-chamber solid oxide fuel cells

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	Fabrication and evaluation of a Ni/La(0.75)Sr(0.25)Cr(0.5)Fe(0.5)O(3-delta) co-impregnated yttria-stabilized zirconia anode for single-chamber solid oxide fuel cells
	X. B. Zhu; Z. Lu; B. Wei; Y. H. Zhang; X. Q. Huang; W. H. Su
	2010
发表期刊	International Journal of Hydrogen Energy
ISSN	0360-3199
卷号	35 期号:13 页码:6897-6904
摘要	In this study, an anode-supported solid oxide fuel cell (SOFC) has been prepared using a porous yttria-stabilized zirconia (YSZ) anode matrix. The anode was prepared by impregnating the sintered porous YSZ matrix with a nitrate aqueous containing La(3+), Sr(2+), Cr(3+), Fe(3+), Ni(2+) and urea. The formed anode exhibited high surface area and porosity, and had fast path for the transportation of oxygen ion and electron, as well as resulting in high three-phase boundaries (TPBs). Single-chamber fuel cell test was conducted in a methane-oxygen gas mixture using an YSZ membrane as the electrolyte and La(0.8)Sr(0.2)MnO(3-delta) (LSM) as the cathode. The influences of environmental temperature and gas composition on the cell performance were also investigated. Under the optimized gas composition (CH(4)/O(2) = 2/1) and furnace temperature (800 degrees C) conditions, a maximum power density of 214 mW cm(-2) was achieved. The test results demonstrated good cell stability and indicated that the perovskite oxide-based anodes were quite robust with redox cycling. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
部门归属	[zhu, xingbao; lue, zhe; wei, bo; zhang, yaohui; huang, xiqiang; su, wenhui] harbin inst technol, dept phys, ctr condensed matter sci & technol, harbin 150080, peoples r china. [su, wenhui] acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;zhu, xb (reprint author), harbin inst technol, dept phys, ctr condensed matter sci & technol, harbin 150080, peoples r china;zhuxingbao008@163.com lvzhe@hit.edu.cn
关键词	Single-chamber Solid Oxide Fuel Cells Perovskite Oxide La(0.75)Sr(0.25)Cr(0.5)Fe(0.5)o(3-delta) Wet Impregnation Redox Cycling Ni Catalyst Supported Sofc Performance Temperature Cathode La0.75sr0.25cr0.5fe0.5o3-delta Methane
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WOS记录号	WOS:000280601600051
引用统计	被引频次：25[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31794
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. B. Zhu,Z. Lu,B. Wei,et al. Fabrication and evaluation of a Ni/La(0.75)Sr(0.25)Cr(0.5)Fe(0.5)O(3-delta) co-impregnated yttria-stabilized zirconia anode for single-chamber solid oxide fuel cells[J]. International Journal of Hydrogen Energy,2010,35(13):6897-6904.
APA	X. B. Zhu,Z. Lu,B. Wei,Y. H. Zhang,X. Q. Huang,&W. H. Su.(2010).Fabrication and evaluation of a Ni/La(0.75)Sr(0.25)Cr(0.5)Fe(0.5)O(3-delta) co-impregnated yttria-stabilized zirconia anode for single-chamber solid oxide fuel cells.International Journal of Hydrogen Energy,35(13),6897-6904.
MLA	X. B. Zhu,et al."Fabrication and evaluation of a Ni/La(0.75)Sr(0.25)Cr(0.5)Fe(0.5)O(3-delta) co-impregnated yttria-stabilized zirconia anode for single-chamber solid oxide fuel cells".International Journal of Hydrogen Energy 35.13(2010):6897-6904.