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Spin canting and spin-flop transition in antiferromagnetic Cr(2)O(3) nanocrystals
D. Li; Z. Han; J. G. Zheng; X. L. Wang; D. Y. Geng; J. Li; Z. D. Zhang
2009
发表期刊Journal of Applied Physics
ISSN0021-8979
卷号106期号:5
摘要The structure and magnetic properties of Cr(2)O(3) and Cr nanoparticles have been investigated. The as-prepared Cr nanoparticles show a core/shell structure, consisting of a Cr core and a thin Cr oxide shell with a thickness of 1.5-2.5 nm. Annealing the Cr nanoparticles in air leads to the formation of Cr(2)O(3) nanoparticles with spherical morphology. The temperature dependence of the magnetization indicates that these Cr(2)O(3) nanocrystals are antiferromagnetic below their Neacuteel temperature of 320 K and undergo an antiferromagnetic to weak-ferromagnetic transition below about 140 K due to spin canting at disordered surfaces. Below 100 K, a spin-flop transition is induced by an external field with a critical field lower than about 7 T.
部门归属[li, d.; han, z.; wang, x. l.; geng, d. y.; li, j.; zhang, z. d.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [li, d.; han, z.; wang, x. l.; geng, d. y.; li, j.; zhang, z. d.] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. [zheng, j. g.] univ calif irvine, calif inst telecommun & informat technol, ctr mat characterizat, lexi, irvine, ca 92697 usa.;li, d (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china;dali@imr.ac.cn
关键词Antiferromagnetic Materials Chromium Chromium Compounds Magnetic Annealing Magnetic Structure Magnetic Transitions Magnetisation Nanostructured Materials Neel Temperature Magnetic-properties Nio Nanoparticles Fine Particles Ferritin Systems
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/32015
专题中国科学院金属研究所
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D. Li,Z. Han,J. G. Zheng,et al. Spin canting and spin-flop transition in antiferromagnetic Cr(2)O(3) nanocrystals[J]. Journal of Applied Physics,2009,106(5).
APA D. Li.,Z. Han.,J. G. Zheng.,X. L. Wang.,D. Y. Geng.,...&Z. D. Zhang.(2009).Spin canting and spin-flop transition in antiferromagnetic Cr(2)O(3) nanocrystals.Journal of Applied Physics,106(5).
MLA D. Li,et al."Spin canting and spin-flop transition in antiferromagnetic Cr(2)O(3) nanocrystals".Journal of Applied Physics 106.5(2009).
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