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Application of scanning electrochemical microscope in the study of corrosion of metals
L. Niu; Y. H. Yin; W. K. Guo; M. Lu; R. J. Qin; S. H. Chen
2009
发表期刊Journal of Materials Science
ISSN0022-2461
卷号44期号:17页码:4511-4521
摘要Scanning electrochemical microscope (SECM) has become a very useful and powerful technique for probing a variety of electrochemical reactions in corrosion process due to its high spatial resolution and electrochemical sensitivity to characterize the topography and redox activities of the metal/electrolyte solution interface. Its capability for the direct identification of chemical species in localized corrosion processes with high spatial resolution would be more advantageous compared to other local probe techniques with only morphological characterization. In this review, the applications of the SECM in the study of early stages of localized corrosion, electroactive defect sites in passive films, local initiation of pits, degradation of coating properties on steels, and some combined methods through SECM integrated with other techniques have been summarized and commented. Finally, the optimization for SECM's experiment design and operation as well as foreseeable application range has been proposed.
部门归属[niu, lin; yin, yuehua; guo, weikuan; lu, min; qin, ruijie; chen, shenhao] shandong univ, sch chem & chem engn, jinan 250100, peoples r china. [chen, shenhao] chinese acad sci, inst met res, shenyang 110016, peoples r china.;niu, l (reprint author), shandong univ, sch chem & chem engn, jinan 250100, peoples r china;lniu@sdu.edu.cn
关键词Imaging Concentration Profiles Austenitic Stainless-steel Phase Ion Gun Pitting Corrosion Localized Corrosion In-situ Impedance Spectroscopy Passive Film Liquid-phase Chloride Solution
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WOS记录号WOS:000268492800001
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被引频次:75[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/32220
专题中国科学院金属研究所
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L. Niu,Y. H. Yin,W. K. Guo,et al. Application of scanning electrochemical microscope in the study of corrosion of metals[J]. Journal of Materials Science,2009,44(17):4511-4521.
APA L. Niu,Y. H. Yin,W. K. Guo,M. Lu,R. J. Qin,&S. H. Chen.(2009).Application of scanning electrochemical microscope in the study of corrosion of metals.Journal of Materials Science,44(17),4511-4521.
MLA L. Niu,et al."Application of scanning electrochemical microscope in the study of corrosion of metals".Journal of Materials Science 44.17(2009):4511-4521.
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