Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal | |
G. Q. Qu; W. C. Zheng; H. G. Liu; W. Q. Yang | |
2009 | |
Source Publication | Molecular Physics
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ISSN | 0026-8976 |
Volume | 107Issue:23-24Pages:2551-2554 |
Abstract | The spin-Hamiltonian parameters (g factor g//, g perpendicular to and hyperfine structure constants A//, A perpendicular to) for Er3+ ion at the trigonal Al3+ site of AlN crystal are calculated by diagonalising the 52 x 52 energy matrix. The matrix are related to the ground mutiplet 4I15/2 and the first to third excited multiplets 4I13/2, 4I11/2 and 4I9/2 for 4f11 ions in trigonal crystal field under an external magnetic field. The crystal-field parameters used in the matrix are obtained from the superposition model and the local lattice relaxation due to the substitution of Er3+ for Al3+ is considered. The calculated spin-Hamiltonian parameters are in reasonable agreement with the experimental values and the signs of hyperfine structure constants are suggested. The results are discussed. |
description.department | [qu, gui-qiang; zheng, wen-chen; liu, hong-gang; yang, wei-qing] sichuan univ, dept mat sci, chengdu 610064, peoples r china. [yang, wei-qing] chengdu univ informat & technol, dept opt & elect, chengdu 610225, peoples r china. [zheng, wen-chen] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china;zhengwc1@163.com |
Keyword | Spin-hamiltonian Parameters Crystal-field Theory Diagonalisation (Of Energy Matrix) Method Er3++ Aln Superposition-model Analysis Epr Parameters Single-crystals Gan Erbium Ion Er Resonance Garnet |
URL | 查看原文 |
WOS ID | WOS:000272898000013 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/32250 |
Collection | 中国科学院金属研究所 |
Recommended Citation GB/T 7714 | G. Q. Qu,W. C. Zheng,H. G. Liu,et al. Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal[J]. Molecular Physics,2009,107(23-24):2551-2554. |
APA | G. Q. Qu,W. C. Zheng,H. G. Liu,&W. Q. Yang.(2009).Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal.Molecular Physics,107(23-24),2551-2554. |
MLA | G. Q. Qu,et al."Investigations of the spin-Hamiltonian parameters for Er3+ions in AlN crystal".Molecular Physics 107.23-24(2009):2551-2554. |
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